(+)-(1S,2S,4S,4aR,5R,6S,9S,10S)-4-Benzyloxy-9,10-(carbonyldioxy) -1-methoxymethoxy-4a,6,-8,8-tetramethyl-7-methylenedodecahydro-6, 9-ethanobenzocyclooctene-5-ol

Shigeru Ohba; Ayako Chinen; Yuki Matsumoto; Noritaka Chida

doi:10.1107/S1600536803019871

(+)-(1S,2S,4S,4aR,5R,6S,9S,10S)-4-Benzyloxy-9,10-(carbonyldioxy) -1-methoxymethoxy-4a,6,-8,8-tetramethyl-7-methylenedodecahydro-6, 9-ethanobenzocyclooctene-5-ol

Shigeru Ohba, Ayako Chinen, Yuki Matsumoto, Noritaka Chida

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title tetracyclic compound, C₂₉H₄₀O₇, has been obtained unexpectedly in a synthetic study of the natural diterpenoid, paclitaxel. There is an intramolecular O-H⋯O hydrogen bond between the hydroxy and benzyloxy groups.

Original language	English
Pages (from-to)	o1476-o1477
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	10
DOIs	https://doi.org/10.1107/S1600536803019871
Publication status	Published - 2003 Oct 1

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536803019871

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(+)-(1S,2S,4S,4aR,5R,6S,9S,10S)-4-Benzyloxy-9,10-(carbonyldioxy) -1-methoxymethoxy-4a,6,-8,8-tetramethyl-7-methylenedodecahydro-6, 9-ethanobenzocyclooctene-5-ol. / Ohba, Shigeru; Chinen, Ayako; Matsumoto, Yuki et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, No. 10, 01.10.2003, p. o1476-o1477.

Research output: Contribution to journal › Article › peer-review

@article{003352b96af74c84a4c3fd0665939c75,

title = "(+)-(1S,2S,4S,4aR,5R,6S,9S,10S)-4-Benzyloxy-9,10-(carbonyldioxy) -1-methoxymethoxy-4a,6,-8,8-tetramethyl-7-methylenedodecahydro-6, 9-ethanobenzocyclooctene-5-ol",

abstract = "The title tetracyclic compound, C29H40O7, has been obtained unexpectedly in a synthetic study of the natural diterpenoid, paclitaxel. There is an intramolecular O-H⋯O hydrogen bond between the hydroxy and benzyloxy groups.",

author = "Shigeru Ohba and Ayako Chinen and Yuki Matsumoto and Noritaka Chida",

year = "2003",

month = oct,

day = "1",

doi = "10.1107/S1600536803019871",

language = "English",

volume = "59",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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}

TY - JOUR

T1 - (+)-(1S,2S,4S,4aR,5R,6S,9S,10S)-4-Benzyloxy-9,10-(carbonyldioxy) -1-methoxymethoxy-4a,6,-8,8-tetramethyl-7-methylenedodecahydro-6, 9-ethanobenzocyclooctene-5-ol

AU - Ohba, Shigeru

AU - Chinen, Ayako

AU - Matsumoto, Yuki

AU - Chida, Noritaka

PY - 2003/10/1

Y1 - 2003/10/1

N2 - The title tetracyclic compound, C29H40O7, has been obtained unexpectedly in a synthetic study of the natural diterpenoid, paclitaxel. There is an intramolecular O-H⋯O hydrogen bond between the hydroxy and benzyloxy groups.

AB - The title tetracyclic compound, C29H40O7, has been obtained unexpectedly in a synthetic study of the natural diterpenoid, paclitaxel. There is an intramolecular O-H⋯O hydrogen bond between the hydroxy and benzyloxy groups.

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U2 - 10.1107/S1600536803019871

DO - 10.1107/S1600536803019871

M3 - Article

AN - SCOPUS:18444409921

SN - 1600-5368

VL - 59

SP - o1476-o1477

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

(+)-(1S,2S,4S,4aR,5R,6S,9S,10S)-4-Benzyloxy-9,10-(carbonyldioxy) -1-methoxymethoxy-4a,6,-8,8-tetramethyl-7-methylenedodecahydro-6, 9-ethanobenzocyclooctene-5-ol

Abstract

ASJC Scopus subject areas

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