(+)-(1S,5R,6R)-6-[(S)-1-Hydroxy-2-(methoxymethyloxy)ethyl] -1-methyl-3-trichloromethyl-2-aza-4,7-dioxabicyclo[3.3.0]oct-2-en-8-one

Takeshi Oishi, Hiroki Oishi, Syun Tsuzaki, Takaaki Sato, Noritaka Chida

Research output: Contribution to journalArticlepeer-review


In the title compound, C11H14Cl3NO6, the fused five-membered oxazoline and tetrahydrofuran rings are essentially planar with maximum deviations of 0.069(1) and 0.031(1)Å, respectively, and make a dihedral angle of 64.23(11)°with each other. In the crystal, molecules are linked by O-H⋯O and C-H⋯O hydrogen bonds, forming chains along the b-axis direction. Further C-H⋯O hydrogen bonds are observed between the chains.

Original languageEnglish
Pages (from-to)o3185
JournalActa Crystallographica Section E: Structure Reports Online
Issue number11
Publication statusPublished - 2012 Nov


  • R factor = 0.027
  • T = 90 K
  • data-to-parameter ratio = 12.2
  • mean ̄(C-C) = 0.003 Å
  • single-crystal X-ray study
  • wR factor = 0.069

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics


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