(+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol

Hiroyuki Hosomi; Shigeru Ohba; Ken Ohmori; Tetsuo Obitsu; Yasuyuki Ogawa; Yuichi Ishikawa; Shosuke Yamamura; Shigeru Nishiyama

doi:10.1107/S0108270100003371

(+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol

Hiroyuki Hosomi
, Shigeru Ohba
, Ken Ohmori
, Tetsuo Obitsu
, Yasuyuki Ogawa
, Yuichi Ishikawa
, Shosuke Yamamura
, Shigeru Nishiyama

Department of Humanities and Social Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The absolute configuration was determined for the title compound. It was prepared in a synthetic study on the natural products, bryostatins. There were 163 Friedel pairs, which were not averaged. The completeness of symmetry unique reactions was 93.3%, which was due to the blind region of the low temperature apparatus. The hydroxyl H atom was located from a difference synthesis. The absolute structure was determined based on a Flack parameter value of 0.03 (3).

Original language	English
Pages (from-to)	e142-e143
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	56
Issue number	4
DOIs	https://doi.org/10.1107/S0108270100003371
Publication status	Published - 2000

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

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title = "(+)-3-\{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl\}prop-2-yn-1-ol",

abstract = "The absolute configuration was determined for the title compound. It was prepared in a synthetic study on the natural products, bryostatins. There were 163 Friedel pairs, which were not averaged. The completeness of symmetry unique reactions was 93.3\%, which was due to the blind region of the low temperature apparatus. The hydroxyl H atom was located from a difference synthesis. The absolute structure was determined based on a Flack parameter value of 0.03 (3).",

author = "Hiroyuki Hosomi and Shigeru Ohba and Ken Ohmori and Tetsuo Obitsu and Yasuyuki Ogawa and Yuichi Ishikawa and Shosuke Yamamura and Shigeru Nishiyama",

year = "2000",

doi = "10.1107/S0108270100003371",

language = "English",

volume = "56",

pages = "e142--e143",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "4",

}

TY - JOUR

T1 - (+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol

AU - Hosomi, Hiroyuki

AU - Ohba, Shigeru

AU - Ohmori, Ken

AU - Obitsu, Tetsuo

AU - Ogawa, Yasuyuki

AU - Ishikawa, Yuichi

AU - Yamamura, Shosuke

AU - Nishiyama, Shigeru

PY - 2000

Y1 - 2000

N2 - The absolute configuration was determined for the title compound. It was prepared in a synthetic study on the natural products, bryostatins. There were 163 Friedel pairs, which were not averaged. The completeness of symmetry unique reactions was 93.3%, which was due to the blind region of the low temperature apparatus. The hydroxyl H atom was located from a difference synthesis. The absolute structure was determined based on a Flack parameter value of 0.03 (3).

AB - The absolute configuration was determined for the title compound. It was prepared in a synthetic study on the natural products, bryostatins. There were 163 Friedel pairs, which were not averaged. The completeness of symmetry unique reactions was 93.3%, which was due to the blind region of the low temperature apparatus. The hydroxyl H atom was located from a difference synthesis. The absolute structure was determined based on a Flack parameter value of 0.03 (3).

UR - https://www.scopus.com/pages/publications/84924985434

UR - https://www.scopus.com/pages/publications/84924985434#tab=citedBy

U2 - 10.1107/S0108270100003371

DO - 10.1107/S0108270100003371

M3 - Article

AN - SCOPUS:84924985434

SN - 0108-2701

VL - 56

SP - e142-e143

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 4

ER -

(+)-3-{(4S,5S)-5-[1,1-dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol

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