Alternating copolymerization of vinyl acetate with carbon monoxide

Takuya Kochi; Akifumi Nakamura; Hirotsugu Ida; Kyoko Nozaki

doi:10.1021/ja072859n

Alternating copolymerization of vinyl acetate with carbon monoxide

Takuya Kochi, Akifumi Nakamura, Hirotsugu Ida, Kyoko Nozaki

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

We report the first example of alternating copolymerization of a polar vinyl monomer and carbon monoxide using vinyl acetate. Alternating copolymers with high molecular weights were prepared employing palladium catalysts with phosphine-sulfonate bidentate ligands. NMR and MALDI-TOF MS analyses revealed that the obtained materials were alternating copolymers of vinyl acetate and carbon monoxide. This is also the first nonradical pathway for polymer synthesis with vinyl acetate, one of the most inexpensive and readily available polar vinyl monomer, as a major component.

Original language	English
Pages (from-to)	7770-7771
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	25
DOIs	https://doi.org/10.1021/ja072859n
Publication status	Published - 2007 Jun 27
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja072859n

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Alternating copolymerization of vinyl acetate with carbon monoxide

Abstract

ASJC Scopus subject areas

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