Anode reactions of a tin thin film electrode modified with an ion-conductive polymer in a room-temperature ionic liquid electrolyte

Y. Kaga, Y. Katayama, T. Miura, S. Komaba

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

The anode reaction of a tin thin film electrode modified with poly(ethyleneoxide) containing lithium bis(trifluoromethylsulfonyl)amide (LiTFSA) has been investigated in an ionic liquid electrolyte, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA). Lithium dope and undope were found possible for the modified electrode, indicating the lithium ion conductive polymer acts as an artificial solid-electrolyte interphase film. The cycle performance of the modified electrode was slightly improved compared with the unmodified one, suggesting the polymer film prevent the active material from falling off from the current collector.

Original languageEnglish
Title of host publicationRechargeable Lithium-Ion Batteries
PublisherElectrochemical Society Inc.
Pages91-98
Number of pages8
Edition36
ISBN (Electronic)9781566778107
ISBN (Print)9781566778107
DOIs
Publication statusPublished - 2009

Publication series

NameECS Transactions
Number36
Volume25
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

ASJC Scopus subject areas

  • Engineering(all)

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