Anodic oxidation on a boron-doped diamond electrode mediated by methoxy radicals

Takenori Sumi; Tsuyoshi Saitoh; Keisuke Natsui; Takashi Yamamoto; Mahito Atobe; Yasuaki Einaga; Shigeru Nishiyama

doi:10.1002/anie.201200878

Anodic oxidation on a boron-doped diamond electrode mediated by methoxy radicals

Takenori Sumi, Tsuyoshi Saitoh, Keisuke Natsui, Takashi Yamamoto, Mahito Atobe, Yasuaki Einaga, Shigeru Nishiyama

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

81 Citations (Scopus)

Abstract

Direct evidence: The existence of methoxy radical species formed during an anodic oxidation in MeOH on a boron-doped diamond (BDD) electrode was confirmed by ESR spectroscopy. Effective production of a neolignan, licarinA, was accomplished by the BDD-mediated anodic oxidation protocol (see picture).

Original language	English
Pages (from-to)	5443-5446
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	22
DOIs	https://doi.org/10.1002/anie.201200878
Publication status	Published - 2012 May 29

Keywords

boron-doped diamond electrode
electrochemistry
electrosynthesis
radicals

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.201200878

Cite this

@article{f799bfc2c9cd4a9e9573473d968def6b,

title = "Anodic oxidation on a boron-doped diamond electrode mediated by methoxy radicals",

abstract = "Direct evidence: The existence of methoxy radical species formed during an anodic oxidation in MeOH on a boron-doped diamond (BDD) electrode was confirmed by ESR spectroscopy. Effective production of a neolignan, licarinA, was accomplished by the BDD-mediated anodic oxidation protocol (see picture).",

keywords = "boron-doped diamond electrode, electrochemistry, electrosynthesis, radicals",

author = "Takenori Sumi and Tsuyoshi Saitoh and Keisuke Natsui and Takashi Yamamoto and Mahito Atobe and Yasuaki Einaga and Shigeru Nishiyama",

year = "2012",

month = may,

day = "29",

doi = "10.1002/anie.201200878",

language = "English",

volume = "51",

pages = "5443--5446",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "22",

}

TY - JOUR

T1 - Anodic oxidation on a boron-doped diamond electrode mediated by methoxy radicals

AU - Sumi, Takenori

AU - Saitoh, Tsuyoshi

AU - Natsui, Keisuke

AU - Yamamoto, Takashi

AU - Atobe, Mahito

AU - Einaga, Yasuaki

AU - Nishiyama, Shigeru

PY - 2012/5/29

Y1 - 2012/5/29

N2 - Direct evidence: The existence of methoxy radical species formed during an anodic oxidation in MeOH on a boron-doped diamond (BDD) electrode was confirmed by ESR spectroscopy. Effective production of a neolignan, licarinA, was accomplished by the BDD-mediated anodic oxidation protocol (see picture).

AB - Direct evidence: The existence of methoxy radical species formed during an anodic oxidation in MeOH on a boron-doped diamond (BDD) electrode was confirmed by ESR spectroscopy. Effective production of a neolignan, licarinA, was accomplished by the BDD-mediated anodic oxidation protocol (see picture).

KW - boron-doped diamond electrode

KW - electrochemistry

KW - electrosynthesis

KW - radicals

UR - http://www.scopus.com/inward/record.url?scp=84861517744&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84861517744&partnerID=8YFLogxK

U2 - 10.1002/anie.201200878

DO - 10.1002/anie.201200878

M3 - Article

C2 - 22514161

AN - SCOPUS:84861517744

SN - 1433-7851

VL - 51

SP - 5443

EP - 5446

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 22

ER -

Anodic oxidation on a boron-doped diamond electrode mediated by methoxy radicals

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this