Biocatalytic one-step synthesis of n-octyl β-D-xylotrioside and xylobioside from xylan and n-octanol in supercritical carbon dioxide

Shuichi Matsumura; Takehiro Nakamura; Eiya Yao; Kazunobu Toshima

doi:10.1246/cl.1999.581

Biocatalytic one-step synthesis of n-octyl β-D-xylotrioside and xylobioside from xylan and n-octanol in supercritical carbon dioxide

Shuichi Matsumura, Takehiro Nakamura, Eiya Yao, Kazunobu Toshima

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

n-Octyl β-D-xylotrioside and xylobioside, which are effective next generation surfactants, can be prepared by the one-step reaction of xylan and n-octanol using acetone powder (acetone-dried cells) of Aureobasidium pullulans KK415 (ATCC 201145) as the enzyme source of xylanase in supercritical carbon dioxide (scCO₂). Yields of the octyl glycosides were significantly increased using scCO₂. Furthermore, without scCO₂, n-octyl xylotrioside was hardly produced.

Original language	English
Pages (from-to)	581-582
Number of pages	2
Journal	Chemistry Letters
Issue number	7
DOIs	https://doi.org/10.1246/cl.1999.581
Publication status	Published - 1999 Jan 1

ASJC Scopus subject areas

Chemistry(all)

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abstract = "n-Octyl β-D-xylotrioside and xylobioside, which are effective next generation surfactants, can be prepared by the one-step reaction of xylan and n-octanol using acetone powder (acetone-dried cells) of Aureobasidium pullulans KK415 (ATCC 201145) as the enzyme source of xylanase in supercritical carbon dioxide (scCO2). Yields of the octyl glycosides were significantly increased using scCO2. Furthermore, without scCO2, n-octyl xylotrioside was hardly produced.",

author = "Shuichi Matsumura and Takehiro Nakamura and Eiya Yao and Kazunobu Toshima",

year = "1999",

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doi = "10.1246/cl.1999.581",

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AU - Matsumura, Shuichi

AU - Nakamura, Takehiro

AU - Yao, Eiya

AU - Toshima, Kazunobu

PY - 1999/1/1

Y1 - 1999/1/1

N2 - n-Octyl β-D-xylotrioside and xylobioside, which are effective next generation surfactants, can be prepared by the one-step reaction of xylan and n-octanol using acetone powder (acetone-dried cells) of Aureobasidium pullulans KK415 (ATCC 201145) as the enzyme source of xylanase in supercritical carbon dioxide (scCO2). Yields of the octyl glycosides were significantly increased using scCO2. Furthermore, without scCO2, n-octyl xylotrioside was hardly produced.

AB - n-Octyl β-D-xylotrioside and xylobioside, which are effective next generation surfactants, can be prepared by the one-step reaction of xylan and n-octanol using acetone powder (acetone-dried cells) of Aureobasidium pullulans KK415 (ATCC 201145) as the enzyme source of xylanase in supercritical carbon dioxide (scCO2). Yields of the octyl glycosides were significantly increased using scCO2. Furthermore, without scCO2, n-octyl xylotrioside was hardly produced.

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Biocatalytic one-step synthesis of n-octyl β-D-xylotrioside and xylobioside from xylan and n-octanol in supercritical carbon dioxide

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