Biochemical preparation of optically active 4-hydroxy-β-ionone and its transformation to (S)-6-hydroxy-α-ionone

Hideaki Kakeya; Takeshi Sugai; Hiromichi Ohta

doi:10.1080/00021369.1991.10870844

Biochemical preparation of optically active 4-hydroxy-β-ionone and its transformation to (S)-6-hydroxy-α-ionone

Hideaki Kakeya, Takeshi Sugai, Hiromichi Ohta

School of Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The preparation of 4-hydroxy-β-ionone of high enantiomeric excess was achieved via lipase-catalyzed transesterification of the corresponding racemate as the key-step. Starting from Its (R)-enantiomer, (S)-6-hydroxy-α-ionone, an important intermediate for synthetic abscisic acid analogs, was synthesized.

Original language	English
Pages (from-to)	1873-1876
Number of pages	4
Journal	Agricultural and biological chemistry
Volume	55
Issue number	7
DOIs	https://doi.org/10.1080/00021369.1991.10870844
Publication status	Published - 1991 Jul

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)
Agricultural and Biological Sciences(all)

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10.1080/00021369.1991.10870844

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abstract = "The preparation of 4-hydroxy-β-ionone of high enantiomeric excess was achieved via lipase-catalyzed transesterification of the corresponding racemate as the key-step. Starting from Its (R)-enantiomer, (S)-6-hydroxy-α-ionone, an important intermediate for synthetic abscisic acid analogs, was synthesized.",

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AU - Sugai, Takeshi

AU - Ohta, Hiromichi

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Biochemical preparation of optically active 4-hydroxy-β-ionone and its transformation to (S)-6-hydroxy-α-ionone

Abstract

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