The crystal structure of the bis(acetone-κO)bis(N,N′- dimethylethylenediamine-κ2N,N′)copper(II) diperchorate was investigated. It was found that an elongated octahedral trans-[CuN 4O2] coordination geometry was adopted by the complex compound. Two ligands, at the axial sites having O-M-O axial acetone bonds, were also observed in the crystal structure of the metal complex. The results show that the bond length for inplane Cu-N is 2.041(3) Å and that for axial Cu-O is 2.507 (5) Å.
|Journal||Acta Crystallographica Section C: Crystal Structure Communications|
|Publication status||Published - 2004 Apr|
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)