TY - JOUR
T1 - Bis(acetone-κO)bis(N,N′-dimethyl ethylenediamine- κ2N,N′)copper(II) diperchlorate
AU - Akitsu, Takashiro
AU - Einaga, Yasuaki
PY - 2004/4
Y1 - 2004/4
N2 - The crystal structure of the bis(acetone-κO)bis(N,N′- dimethylethylenediamine-κ2N,N′)copper(II) diperchorate was investigated. It was found that an elongated octahedral trans-[CuN 4O2] coordination geometry was adopted by the complex compound. Two ligands, at the axial sites having O-M-O axial acetone bonds, were also observed in the crystal structure of the metal complex. The results show that the bond length for inplane Cu-N is 2.041(3) Å and that for axial Cu-O is 2.507 (5) Å.
AB - The crystal structure of the bis(acetone-κO)bis(N,N′- dimethylethylenediamine-κ2N,N′)copper(II) diperchorate was investigated. It was found that an elongated octahedral trans-[CuN 4O2] coordination geometry was adopted by the complex compound. Two ligands, at the axial sites having O-M-O axial acetone bonds, were also observed in the crystal structure of the metal complex. The results show that the bond length for inplane Cu-N is 2.041(3) Å and that for axial Cu-O is 2.507 (5) Å.
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U2 - 10.1107/S010827010400349X
DO - 10.1107/S010827010400349X
M3 - Article
C2 - 15071204
AN - SCOPUS:2442465003
SN - 0108-2701
VL - 60
SP - m162-m164
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 4
ER -