TY - JOUR
T1 - Borinic acid catalyzed 1, 2-cis-stereoselective glycosylations and their applications to the total synthesis of natural products
AU - Takahashi, Daisuke
N1 - Publisher Copyright:
© 2018 Society of Synthetic Organic Chemistry. All rights reserved.
PY - 2018
Y1 - 2018
N2 - In this mini-review article, d (i 4-fluoro) phenylborinic acid ( 3c) catalyzed 1, 2-cis-a and ß - stereoselective glycosylations using 1, 2-anhydroglucose donor 8 and 1, 2-anhydromannose donor 11, respectively, that have recently been developed in our laboratory, are introduced. In addition, representative applications of these glycosylation methods to the stereoselective synthesis of biologically active natural products, GSL-1 and acremomannolipin A, are also introduced.
AB - In this mini-review article, d (i 4-fluoro) phenylborinic acid ( 3c) catalyzed 1, 2-cis-a and ß - stereoselective glycosylations using 1, 2-anhydroglucose donor 8 and 1, 2-anhydromannose donor 11, respectively, that have recently been developed in our laboratory, are introduced. In addition, representative applications of these glycosylation methods to the stereoselective synthesis of biologically active natural products, GSL-1 and acremomannolipin A, are also introduced.
KW - 1,2-cis-glycoside
KW - Borinic acid
KW - Glycosylation
KW - Natural glycolipid
KW - Stereoselective
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U2 - 10.5059/yukigoseikyokaishi.76.470
DO - 10.5059/yukigoseikyokaishi.76.470
M3 - Article
AN - SCOPUS:85046900265
SN - 0037-9980
VL - 76
SP - 470
EP - 473
JO - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
JF - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
IS - 5
ER -