C-arylglycosylation of unprotected free sugar

Kazunobu Toshima, Goh Matsuo, Toru Ishizuka, Masaya Nakata, Mitsuhiro Kinoshita

Research output: Contribution to journalArticlepeer-review

33 Citations (Scopus)


Highly regio- and stereo-selective C-arylglycosylations of the protected free sugars 1-4, the unprotected methyl glycosides 6-9 and the unprotected free sugars 10 and 11 with 2-naphthol 5 are effectively realized by the combined use of TMSOTf-AgClO4 (TMSOTf = trimethylsilyloxytrifluoromethanesulfonate) as a catalytic activator.

Original languageEnglish
Pages (from-to)1641-1642
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number22
Publication statusPublished - 1992

ASJC Scopus subject areas

  • Molecular Medicine


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