Catalytic addition of C-H bonds to multiple bonds with the aid of ruthenium complexes

Shinji Murai; Naoto Chatani; Fumitoshi Kakiuchi

doi:10.1023/A:1019064627386

Catalytic addition of C-H bonds to multiple bonds with the aid of ruthenium complexes

Shinji Murai, Naoto Chatani, Fumitoshi Kakiuchi

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Ruthenium complexes, e.g., RuH₂(CO)(PPh₃)₃, have been found to catalyze the direct addition of ortho carbon-hydrogen bonds of aromatic ketones to olefins and acetylenes with high efficiency and selectivity. The C-H/olefin coupling reaction is applicable to not only C-H bonds in aromatic ketones but also to those in α,β-enones and aromatic esters. Catalytic addition of ortho carbon-hydrogen bonds of aromatic imines to olefins is found to be catalyzed by Ru₃(CO)₁₂.

Original language	English
Pages (from-to)	35-51
Number of pages	17
Journal	Catalysis Surveys from Japan
Volume	1
Issue number	1
DOIs	https://doi.org/10.1023/A:1019064627386
Publication status	Published - 1997 Jan 1
Externally published	Yes

Keywords

Aromatic ester
Aromatic imine
Aromatic ketone
C-H/acetylene coupling
C-H/olefin coupling
Carbon-hydrogen bond cleavage
Ruthenium
α,β-enone

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

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title = "Catalytic addition of C-H bonds to multiple bonds with the aid of ruthenium complexes",

abstract = "Ruthenium complexes, e.g., RuH2(CO)(PPh3)3, have been found to catalyze the direct addition of ortho carbon-hydrogen bonds of aromatic ketones to olefins and acetylenes with high efficiency and selectivity. The C-H/olefin coupling reaction is applicable to not only C-H bonds in aromatic ketones but also to those in α,β-enones and aromatic esters. Catalytic addition of ortho carbon-hydrogen bonds of aromatic imines to olefins is found to be catalyzed by Ru3(CO)12.",

keywords = "Aromatic ester, Aromatic imine, Aromatic ketone, C-H/acetylene coupling, C-H/olefin coupling, Carbon-hydrogen bond cleavage, Ruthenium, α,β-enone",

author = "Shinji Murai and Naoto Chatani and Fumitoshi Kakiuchi",

year = "1997",

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language = "English",

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T1 - Catalytic addition of C-H bonds to multiple bonds with the aid of ruthenium complexes

AU - Murai, Shinji

AU - Chatani, Naoto

AU - Kakiuchi, Fumitoshi

PY - 1997/1/1

Y1 - 1997/1/1

N2 - Ruthenium complexes, e.g., RuH2(CO)(PPh3)3, have been found to catalyze the direct addition of ortho carbon-hydrogen bonds of aromatic ketones to olefins and acetylenes with high efficiency and selectivity. The C-H/olefin coupling reaction is applicable to not only C-H bonds in aromatic ketones but also to those in α,β-enones and aromatic esters. Catalytic addition of ortho carbon-hydrogen bonds of aromatic imines to olefins is found to be catalyzed by Ru3(CO)12.

AB - Ruthenium complexes, e.g., RuH2(CO)(PPh3)3, have been found to catalyze the direct addition of ortho carbon-hydrogen bonds of aromatic ketones to olefins and acetylenes with high efficiency and selectivity. The C-H/olefin coupling reaction is applicable to not only C-H bonds in aromatic ketones but also to those in α,β-enones and aromatic esters. Catalytic addition of ortho carbon-hydrogen bonds of aromatic imines to olefins is found to be catalyzed by Ru3(CO)12.

KW - Aromatic ester

KW - Aromatic imine

KW - Aromatic ketone

KW - C-H/acetylene coupling

KW - C-H/olefin coupling

KW - Carbon-hydrogen bond cleavage

KW - Ruthenium

KW - α,β-enone

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Catalytic addition of C-H bonds to multiple bonds with the aid of ruthenium complexes

Abstract

Keywords

ASJC Scopus subject areas

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