Catalytic Conjugate Additions of Alkynes

Naoya Kumagai; Masakatsu Shibasaki

doi:10.1002/9783527677894.ch7

Catalytic Conjugate Additions of Alkynes

Naoya Kumagai, Masakatsu Shibasaki

Research output: Chapter in Book/Report/Conference proceeding › Chapter

1 Citation (Scopus)

Abstract

Recent advances in conjugate addition of alkynes are summarized. Since the initial developments using metalated alkynes, the focus of this field has shifted to the direct use of terminal alkynes through advanced catalytic systems. Several examples of enantioselective catalysis have allowed us to produce synthetically versatile enantioenriched β-alkynyl carbonyl compounds.

Original language	English
Title of host publication	Modern Alkyne Chemistry
Subtitle of host publication	Catalytic and Atom-Economic Transformations
Publisher	Wiley Blackwell
Pages	171-200
Number of pages	30
Volume	9783527335053
ISBN (Electronic)	9783527677894
ISBN (Print)	9783527335053
DOIs	https://doi.org/10.1002/9783527677894.ch7
Publication status	Published - 2015 Feb 9
Externally published	Yes

Keywords

Metal alkynylide
Terminal alkyne
α,β-unsaturated compounds
β-alkynyl carbonyl compounds

ASJC Scopus subject areas

Chemistry(all)

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10.1002/9783527677894.ch7

Cite this

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abstract = "Recent advances in conjugate addition of alkynes are summarized. Since the initial developments using metalated alkynes, the focus of this field has shifted to the direct use of terminal alkynes through advanced catalytic systems. Several examples of enantioselective catalysis have allowed us to produce synthetically versatile enantioenriched β-alkynyl carbonyl compounds.",

keywords = "Metal alkynylide, Terminal alkyne, α,β-unsaturated compounds, β-alkynyl carbonyl compounds",

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AU - Shibasaki, Masakatsu

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AB - Recent advances in conjugate addition of alkynes are summarized. Since the initial developments using metalated alkynes, the focus of this field has shifted to the direct use of terminal alkynes through advanced catalytic systems. Several examples of enantioselective catalysis have allowed us to produce synthetically versatile enantioenriched β-alkynyl carbonyl compounds.

KW - Metal alkynylide

KW - Terminal alkyne

KW - α,β-unsaturated compounds

KW - β-alkynyl carbonyl compounds

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ER -

Catalytic Conjugate Additions of Alkynes

Abstract

Keywords

ASJC Scopus subject areas

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