Catalytic electrochemical C-H iodination and one-pot arylation by ON/OFF switching of electric current

Hiroko Aiso; Takuya Kochi; Hitoshi Mutsutani; Takamasa Tanabe; Shigeru Nishiyama; Fumitoshi Kakiuchi

doi:10.1021/jo3012286

Catalytic electrochemical C-H iodination and one-pot arylation by ON/OFF switching of electric current

Hiroko Aiso, Takuya Kochi, Hitoshi Mutsutani, Takamasa Tanabe, Shigeru Nishiyama, Fumitoshi Kakiuchi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

96 Citations (Scopus)

Abstract

Palladium-catalyzed electrochemical iodination and one-pot arylation of arylpyridines are described. Ortho-selective C-H iodination proceeded via dual activation of each substrate by a palladium catalyst and an electrode. Various aryl groups were introduced at the ortho positions of arylpyridines by ON/OFF switching of two different catalytic cycles using the same palladium catalyst in a one-pot fashion.

Original language	English
Pages (from-to)	7718-7724
Number of pages	7
Journal	Journal of Organic Chemistry
Volume	77
Issue number	17
DOIs	https://doi.org/10.1021/jo3012286
Publication status	Published - 2012 Sept 7

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1021/jo3012286

Cite this

@article{294c7dacb1504d55a98e5483e3214bb4,

title = "Catalytic electrochemical C-H iodination and one-pot arylation by ON/OFF switching of electric current",

abstract = "Palladium-catalyzed electrochemical iodination and one-pot arylation of arylpyridines are described. Ortho-selective C-H iodination proceeded via dual activation of each substrate by a palladium catalyst and an electrode. Various aryl groups were introduced at the ortho positions of arylpyridines by ON/OFF switching of two different catalytic cycles using the same palladium catalyst in a one-pot fashion.",

author = "Hiroko Aiso and Takuya Kochi and Hitoshi Mutsutani and Takamasa Tanabe and Shigeru Nishiyama and Fumitoshi Kakiuchi",

year = "2012",

month = sep,

day = "7",

doi = "10.1021/jo3012286",

language = "English",

volume = "77",

pages = "7718--7724",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "17",

}

TY - JOUR

T1 - Catalytic electrochemical C-H iodination and one-pot arylation by ON/OFF switching of electric current

AU - Aiso, Hiroko

AU - Kochi, Takuya

AU - Mutsutani, Hitoshi

AU - Tanabe, Takamasa

AU - Nishiyama, Shigeru

AU - Kakiuchi, Fumitoshi

PY - 2012/9/7

Y1 - 2012/9/7

N2 - Palladium-catalyzed electrochemical iodination and one-pot arylation of arylpyridines are described. Ortho-selective C-H iodination proceeded via dual activation of each substrate by a palladium catalyst and an electrode. Various aryl groups were introduced at the ortho positions of arylpyridines by ON/OFF switching of two different catalytic cycles using the same palladium catalyst in a one-pot fashion.

AB - Palladium-catalyzed electrochemical iodination and one-pot arylation of arylpyridines are described. Ortho-selective C-H iodination proceeded via dual activation of each substrate by a palladium catalyst and an electrode. Various aryl groups were introduced at the ortho positions of arylpyridines by ON/OFF switching of two different catalytic cycles using the same palladium catalyst in a one-pot fashion.

UR - http://www.scopus.com/inward/record.url?scp=84866066728&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84866066728&partnerID=8YFLogxK

U2 - 10.1021/jo3012286

DO - 10.1021/jo3012286

M3 - Article

C2 - 22881601

AN - SCOPUS:84866066728

SN - 0022-3263

VL - 77

SP - 7718

EP - 7724

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 17

ER -

Catalytic electrochemical C-H iodination and one-pot arylation by ON/OFF switching of electric current

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this