Chain-walking cycloisomerization of 1,n-dienes catalyzed by pyridine-oxazoline palladium catalysts and its application to asymmetric synthesis

Taro Hamasaki; Fumitoshi Kakiuchi; Takuya Kochi

doi:10.1246/cl.151138

Chain-walking cycloisomerization of 1,n-dienes catalyzed by pyridine-oxazoline palladium catalysts and its application to asymmetric synthesis

Taro Hamasaki, Fumitoshi Kakiuchi, Takuya Kochi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Palladium catalysts possessing pyridineoxazoline ligands were found to catalyze the chain-walking cycloisomerization of 1,n-dienes to form five-membered rings and were particularly effective for the reaction of 1,14-dienes. Asymmetric synthesis of cyclopentane derivatives was also achieved for the reaction of 1,n-dienes using chiral pyridineoxazoline ligands.

Original language	English
Pages (from-to)	297-299
Number of pages	3
Journal	Chemistry Letters
Volume	45
Issue number	3
DOIs	https://doi.org/10.1246/cl.151138
Publication status	Published - 2016

Keywords

Asymmetric synthesis
Chain-walking cycloisomerization
Pyridine-oxazoline palladium catalyst

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.151138

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title = "Chain-walking cycloisomerization of 1,n-dienes catalyzed by pyridine-oxazoline palladium catalysts and its application to asymmetric synthesis",

abstract = "Palladium catalysts possessing pyridineoxazoline ligands were found to catalyze the chain-walking cycloisomerization of 1,n-dienes to form five-membered rings and were particularly effective for the reaction of 1,14-dienes. Asymmetric synthesis of cyclopentane derivatives was also achieved for the reaction of 1,n-dienes using chiral pyridineoxazoline ligands.",

keywords = "Asymmetric synthesis, Chain-walking cycloisomerization, Pyridine-oxazoline palladium catalyst",

author = "Taro Hamasaki and Fumitoshi Kakiuchi and Takuya Kochi",

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year = "2016",

doi = "10.1246/cl.151138",

language = "English",

volume = "45",

pages = "297--299",

journal = "Chemistry Letters",

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T1 - Chain-walking cycloisomerization of 1,n-dienes catalyzed by pyridine-oxazoline palladium catalysts and its application to asymmetric synthesis

AU - Hamasaki, Taro

AU - Kakiuchi, Fumitoshi

AU - Kochi, Takuya

PY - 2016

Y1 - 2016

N2 - Palladium catalysts possessing pyridineoxazoline ligands were found to catalyze the chain-walking cycloisomerization of 1,n-dienes to form five-membered rings and were particularly effective for the reaction of 1,14-dienes. Asymmetric synthesis of cyclopentane derivatives was also achieved for the reaction of 1,n-dienes using chiral pyridineoxazoline ligands.

AB - Palladium catalysts possessing pyridineoxazoline ligands were found to catalyze the chain-walking cycloisomerization of 1,n-dienes to form five-membered rings and were particularly effective for the reaction of 1,14-dienes. Asymmetric synthesis of cyclopentane derivatives was also achieved for the reaction of 1,n-dienes using chiral pyridineoxazoline ligands.

KW - Asymmetric synthesis

KW - Chain-walking cycloisomerization

KW - Pyridine-oxazoline palladium catalyst

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JF - Chemistry Letters

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ER -

Chain-walking cycloisomerization of 1,n-dienes catalyzed by pyridine-oxazoline palladium catalysts and its application to asymmetric synthesis

Abstract

Keywords

ASJC Scopus subject areas

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