Charged fluorophores-assisted fabrication of metallic structures inside hydrogel by multi-photon photoreduction

Manan MacHida, Weilu Shen, Hiroaki Onoe, Alexander Heisterkamp, Eric Mazur, Mitsuhiro Terakawa

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

We demonstrated the fabrication of gold microstructures inside a PEG-based hydrogel with different charged fluorophores by multi-photon photoreduction. By adding an anionic charged FITC-dextran or a cationic charged Rhodamine110 to the metal ion solution, line width of the fabricated gold microstructures increased compared to that of the structures fabricated in fluorophore-free hydrogel. The photobleaching could enhanced the reduction of gold ions accompanying the oxidation of the fluorophores. Notably, the inhibition of reduction of gold ions at a site other than the focal point was observed with FITC-dextran, which may be attributable to the coordination of gold ions to FITC-dextran.

Original languageEnglish
Title of host publicationFrontiers in Ultrafast Optics
Subtitle of host publicationBiomedical, Scientific, and Industrial Applications XXI
EditorsPeter R. Herman, Michel Meunier, Roberto Osellame
PublisherSPIE
ISBN (Electronic)9781510641877
DOIs
Publication statusPublished - 2021
EventFrontiers in Ultrafast Optics: Biomedical, Scientific, and Industrial Applications XXI 2021 - Virtual, Online, United States
Duration: 2021 Mar 62021 Mar 11

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume11676
ISSN (Print)0277-786X
ISSN (Electronic)1996-756X

Conference

ConferenceFrontiers in Ultrafast Optics: Biomedical, Scientific, and Industrial Applications XXI 2021
Country/TerritoryUnited States
CityVirtual, Online
Period21/3/621/3/11

Keywords

  • Femtosecond laser
  • Fluorophore
  • Gold
  • Hydrogel
  • Microfabrication
  • Photoreduction
  • Soft material

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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