Chloro(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato -κ4N)iron(III) chloroform solvate

Yoshiki Ohgo, Saburo Neya, Takahisa Ikeue, Noriaki Funasaki, Mikio Nakamura

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)


The X-ray crystallographic analysis of the title complex, chloro[3,10,13,20-tetraethyl-4,9,14,19-tetramethylpentacyclo [,5.18,11.112,15] tetracosa-2,4,6,8(23),9,12,14,16,18(21),19-decaene]iron(III) chloroform solvate, [Fe(C33H37N4)Cl]·CHCl3, reveals a twisted macrocyclic framework with a slightly distorted rectangular pyramidal core, where the deviation of the central FeIII atom from the least-squares plane of the C20N4 core is 0.594 (1) Å. Some important bond distances are as follows: Fe-N 2.019 (3), 2.026 (3), 2.028 (3) and 2.034 (3) Å; Fe-Cl 2.232 (1) Å.

Original languageEnglish
Pages (from-to)1046-1047
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Issue number9
Publication statusPublished - 2001 Sept
Externally publishedYes

ASJC Scopus subject areas

  • General Biochemistry,Genetics and Molecular Biology


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