Coexistence of Solvated Electrons and Solvent Valence Anions in Negatively Charged Acetonitrile Clusters, (CH3CN)n- (n = 10-100)

Masaaki Mitsui; Naoto Ando; Shinsuke Kokubo; Atsushi Nakajima; Koji Kaya

Coexistence of Solvated Electrons and Solvent Valence Anions in Negatively Charged Acetonitrile Clusters, (CH₃CN)_n^- (n = 10-100)

Masaaki Mitsui, Naoto Ando, Shinsuke Kokubo, Atsushi Nakajima, Koji Kaya

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

The coexistence of solvated electrons and solvent valence anions in negatively charged acetonitrile clusters, (CH₃CN)^- _n (n=10-100) was discussed. The distinctly different nature of the anions were found to be revealed by hole-burning-type photoelectron spectroscopy. The analysis showed that the coexistence was due to the closely lying nature of their anionic state at just the number of solvent molecules sufficient to almost to complete the first solvation layer.

Original language	English
Article number	153002
Pages (from-to)	1530021-1530024
Number of pages	4
Journal	Physical review letters
Volume	91
Issue number	15
Publication status	Published - 2003 Oct 10

ASJC Scopus subject areas

Physics and Astronomy(all)

Cite this

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abstract = "The coexistence of solvated electrons and solvent valence anions in negatively charged acetonitrile clusters, (CH3CN)- n (n=10-100) was discussed. The distinctly different nature of the anions were found to be revealed by hole-burning-type photoelectron spectroscopy. The analysis showed that the coexistence was due to the closely lying nature of their anionic state at just the number of solvent molecules sufficient to almost to complete the first solvation layer.",

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AU - Mitsui, Masaaki

AU - Ando, Naoto

AU - Kokubo, Shinsuke

AU - Nakajima, Atsushi

AU - Kaya, Koji

PY - 2003/10/10

Y1 - 2003/10/10

N2 - The coexistence of solvated electrons and solvent valence anions in negatively charged acetonitrile clusters, (CH3CN)- n (n=10-100) was discussed. The distinctly different nature of the anions were found to be revealed by hole-burning-type photoelectron spectroscopy. The analysis showed that the coexistence was due to the closely lying nature of their anionic state at just the number of solvent molecules sufficient to almost to complete the first solvation layer.

AB - The coexistence of solvated electrons and solvent valence anions in negatively charged acetonitrile clusters, (CH3CN)- n (n=10-100) was discussed. The distinctly different nature of the anions were found to be revealed by hole-burning-type photoelectron spectroscopy. The analysis showed that the coexistence was due to the closely lying nature of their anionic state at just the number of solvent molecules sufficient to almost to complete the first solvation layer.

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Coexistence of Solvated Electrons and Solvent Valence Anions in Negatively Charged Acetonitrile Clusters, (CH₃CN)_n^- (n = 10-100)

Abstract

ASJC Scopus subject areas

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