Complexation of europium ion with poly(methacrylic acid)s and fluorescent property of the complexes

H. Nishide; T. Izushi; N. Yoshioka; E. Tsuchida

doi:10.1007/BF00263452

Complexation of europium ion with poly(methacrylic acid)s and fluorescent property of the complexes

H. Nishide, T. Izushi, N. Yoshioka, E. Tsuchida

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The complexation of europium ion(Eu³⁺) with poly(methacrylic acid) and its copolymers was studied. Poly(methacrylic acid-co-acrylamide) formed the tris(carboxylate)-coordinate Eu complex with extra large overall complexation constant while poly(methacrylic acid)s did the bis-coordinate ones. Transparent and flexible film containing much Eu ion was prepared by casting the complex solution of poly(methacrylic acid-co-methylacrylate). On exposure to ultraviolet light (393 nm), the film relatively strongly fluorescenced a red color based on the tris-coordinate and uniformly dispersed Eu complex.

Original language	English
Pages (from-to)	387-392
Number of pages	6
Journal	Polymer Bulletin
Volume	14
Issue number	5
DOIs	https://doi.org/10.1007/BF00263452
Publication status	Published - 1985 Nov 1
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Condensed Matter Physics
Polymers and Plastics
Materials Chemistry

Access to Document

10.1007/BF00263452

Cite this

@article{053c2b155dd348af87aef84f96b17633,

title = "Complexation of europium ion with poly(methacrylic acid)s and fluorescent property of the complexes",

abstract = "The complexation of europium ion(Eu3+) with poly(methacrylic acid) and its copolymers was studied. Poly(methacrylic acid-co-acrylamide) formed the tris(carboxylate)-coordinate Eu complex with extra large overall complexation constant while poly(methacrylic acid)s did the bis-coordinate ones. Transparent and flexible film containing much Eu ion was prepared by casting the complex solution of poly(methacrylic acid-co-methylacrylate). On exposure to ultraviolet light (393 nm), the film relatively strongly fluorescenced a red color based on the tris-coordinate and uniformly dispersed Eu complex.",

author = "H. Nishide and T. Izushi and N. Yoshioka and E. Tsuchida",

year = "1985",

month = nov,

day = "1",

doi = "10.1007/BF00263452",

language = "English",

volume = "14",

pages = "387--392",

journal = "Polymer Bulletin",

issn = "0170-0839",

publisher = "Springer Verlag",

number = "5",

}

TY - JOUR

T1 - Complexation of europium ion with poly(methacrylic acid)s and fluorescent property of the complexes

AU - Nishide, H.

AU - Izushi, T.

AU - Yoshioka, N.

AU - Tsuchida, E.

PY - 1985/11/1

Y1 - 1985/11/1

N2 - The complexation of europium ion(Eu3+) with poly(methacrylic acid) and its copolymers was studied. Poly(methacrylic acid-co-acrylamide) formed the tris(carboxylate)-coordinate Eu complex with extra large overall complexation constant while poly(methacrylic acid)s did the bis-coordinate ones. Transparent and flexible film containing much Eu ion was prepared by casting the complex solution of poly(methacrylic acid-co-methylacrylate). On exposure to ultraviolet light (393 nm), the film relatively strongly fluorescenced a red color based on the tris-coordinate and uniformly dispersed Eu complex.

AB - The complexation of europium ion(Eu3+) with poly(methacrylic acid) and its copolymers was studied. Poly(methacrylic acid-co-acrylamide) formed the tris(carboxylate)-coordinate Eu complex with extra large overall complexation constant while poly(methacrylic acid)s did the bis-coordinate ones. Transparent and flexible film containing much Eu ion was prepared by casting the complex solution of poly(methacrylic acid-co-methylacrylate). On exposure to ultraviolet light (393 nm), the film relatively strongly fluorescenced a red color based on the tris-coordinate and uniformly dispersed Eu complex.

UR - http://www.scopus.com/inward/record.url?scp=0022150208&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0022150208&partnerID=8YFLogxK

U2 - 10.1007/BF00263452

DO - 10.1007/BF00263452

M3 - Article

AN - SCOPUS:0022150208

SN - 0170-0839

VL - 14

SP - 387

EP - 392

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 5

ER -

Complexation of europium ion with poly(methacrylic acid)s and fluorescent property of the complexes

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this