Convenient synthesis of Tetra- And hexaarylanthracenes by means of RuH2(CO)(PPh3)3-Catalyzed C-H Arylation of Anthraquinone with Arylboronates

Kentaroh Kitazawa; Takuya Kochi; Mitsuo Sato; Fumitoshi Kakiuchi

doi:10.1021/ol900393x

Convenient synthesis of Tetra- And hexaarylanthracenes by means of RuH2(CO)(PPh3)3-Catalyzed C-H Arylation of Anthraquinone with Arylboronates

Kentaroh Kitazawa, Takuya Kochi, Mitsuo Sato, Fumitoshi Kakiuchi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

A new method for the synthesis of multiarylanthracenes was developed by means of the RuH₂(CO)(PPh₃)₃-catalyzed arylation of anthraquinone with arylboronates. This method consists of short and straightforward sequences starting with an easily accessible anthraquinone and is applicable to the syntheses of various multiarylanthracenes including those bearing twisted backbones.

Original language	English
Pages (from-to)	1951-1954
Number of pages	4
Journal	Organic Letters
Volume	11
Issue number	9
DOIs	https://doi.org/10.1021/ol900393x
Publication status	Published - 2009 May 7

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol900393x

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abstract = "A new method for the synthesis of multiarylanthracenes was developed by means of the RuH2(CO)(PPh3)3-catalyzed arylation of anthraquinone with arylboronates. This method consists of short and straightforward sequences starting with an easily accessible anthraquinone and is applicable to the syntheses of various multiarylanthracenes including those bearing twisted backbones.",

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AU - Sato, Mitsuo

AU - Kakiuchi, Fumitoshi

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Convenient synthesis of Tetra- And hexaarylanthracenes by means of RuH2(CO)(PPh3)3-Catalyzed C-H Arylation of Anthraquinone with Arylboronates

Abstract

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