Cooperative spin-crossover transition from three-dimensional purely π-stacking interactions in a neutral heteroleptic azobisphenolate FeIII complex with a N3O3 coordination sphere

Suguru Murata; Kazuyuki Takahashi; Tomoyuki Mochida; Takahiro Sakurai; Hitoshi Ohta; Takashi Yamamoto; Yasuaki Einaga

doi:10.1039/c7dt01030c

Cooperative spin-crossover transition from three-dimensional purely π-stacking interactions in a neutral heteroleptic azobisphenolate Fe^III complex with a N₃O₃ coordination sphere

Suguru Murata, Kazuyuki Takahashi, Tomoyuki Mochida, Takahiro Sakurai, Hitoshi Ohta, Takashi Yamamoto, Yasuaki Einaga

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

A novel neutral heteroleptic Fe^III complex from two kinds of π-extended tridentate ligands was designed and prepared. The π-ligands formed a three-dimensional purely π-stacking interaction network. The present complex proved to be the first neutral spin-crossover (SCO) Fe^III complex with a N₃O₃ coordination sphere exhibiting an abrupt SCO transition with a thermal hysteresis of 10 K and the light-induced excited spin-state trapping effect.

Original language	English
Pages (from-to)	5786-5789
Number of pages	4
Journal	Dalton Transactions
Volume	46
Issue number	18
DOIs	https://doi.org/10.1039/c7dt01030c
Publication status	Published - 2017

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/c7dt01030c

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Cooperative spin-crossover transition from three-dimensional purely π-stacking interactions in a neutral heteroleptic azobisphenolate Fe^III complex with a N₃O₃ coordination sphere. / Murata, Suguru; Takahashi, Kazuyuki; Mochida, Tomoyuki et al.
In: Dalton Transactions, Vol. 46, No. 18, 2017, p. 5786-5789.

Research output: Contribution to journal › Article › peer-review

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AU - Sakurai, Takahiro

AU - Ohta, Hitoshi

AU - Yamamoto, Takashi

AU - Einaga, Yasuaki

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Cooperative spin-crossover transition from three-dimensional purely π-stacking interactions in a neutral heteroleptic azobisphenolate Fe^III complex with a N₃O₃ coordination sphere

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