Coupled Exfoliation and Surface Functionalization of Titanate Monolayer for Bandgap Engineering

Yuna Yamamoto, Yuya Oaki, Hiroaki Imai

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)


Exfoliation of layered compounds generates nanosheets, such as monolayers and few-layers. In general, it is not easy to control surface chemistry of the exfoliated nanosheets. Here, a new approach for surface functionalization of titanate monolayer coupled with exfoliation is reported. The precursor layered composite is prepared by intercalation of long-chain alkyl-ammonium ion, such as stearylammonium ion (C18NH3 +), in the interlayer space of layered titanate. The layered composite of titanate and C18NH3 + (C18TiO2) is dispersed in the toluene solution containing dihydroxynaphthalene (DHN) for the coupled exfoliation and surface modification. The surface molecule is partially exchanged from the original C18NH3 + to the guest DHN. The resultant hydrophobic titanate monolayer with surface modification by the C18NH3 + and DHN (DHN/C18TiO2) shows the visible-light absorption based on the charge-transfer excitation from the highest occupied molecular orbital of the adsorbed DHN to the conduction band of the titanate. The present synthetic approach can be applied to synthesis of a variety of surface-functionalized monolayers and their bandgap engineering.

Original languageEnglish
Article number1601014
JournalAdvanced Materials Interfaces
Issue number7
Publication statusPublished - 2017 Apr 7


  • bandgap engineering
  • exfoliation
  • nanosheets
  • surface functionalization
  • titanate

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering


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