@article{fe3a6d5efefc45479023c85b9963c5fd,
title = "Dearomative Oxidative Rearrangement of [3]Cyclo-1,8-carbazolylene",
abstract = "[3]Cyclo-1,8-carbazolylene was found to undergo oxidative rearrangement by oxidation with 2,3-dichloro-5,6-dicyano-pbenzoquinone, giving a 9a-substituted carbazol-1-one derivative. This is the first example of a dearomative oxidative rearrangement of a carbazole or aniline derivative. The geometrical and electronic structures were elucidated by X-ray analysis, UV-vis absorption spectroscopy, and DFT calculations.",
keywords = "Carbazole, Oxidation, Rearrangement",
author = "Masamichi Yasui and Hiroyoshi Ohtsu and Masaki Kawano and Kengo Hanaya and Takeshi Sugai and Shuhei Higashibayashi",
note = "Funding Information: This work was supported by the Japan Society for the Promotion of Science (JSPS) KAKENHI Grant Numbers 17K19131 (S. H.), 26102002 (S. H.), and JST ACT-C Grant Number JPMJCR12YZ (S. H.). The X-ray diffraction study of 10 with synchrotron radiation was performed at the Pohang Accelerator Laboratory (Beamline 2D) supported by POSTECH. Publisher Copyright: {\textcopyright} 2018 The Chemical Society of Japan.",
year = "2018",
doi = "10.1246/cl.180637",
language = "English",
volume = "47",
pages = "1357--1359",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "11",
}