Dehydrogenative Silylation of 1,5-Dienes with Hydrosilanes Catalyzed by RhCl(PPh3)3

Fumitoshi Kakiuchi; Katsuo Nogami; Naoto Chatani; Yoshio Seki; Shinji Murai

doi:10.1021/om00036a013

Dehydrogenative Silylation of 1,5-Dienes with Hydrosilanes Catalyzed by RhCl(PPh₃)₃

Fumitoshi Kakiuchi, Katsuo Nogami, Naoto Chatani, Yoshio Seki, Shinji Murai

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

The reaction of 1,5-dienes with hydrosilanes using RhCl(PPh₃)₃ as a catalyst gives 1-silyl-1,5-dienes as the result of dehydrogenative silylation instead of the usual hydrosilylation products.

Original language	English
Pages (from-to)	4748-4750
Number of pages	3
Journal	Organometallics
Volume	12
Issue number	12
DOIs	https://doi.org/10.1021/om00036a013
Publication status	Published - 1993
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om00036a013

Cite this

@article{4aecdbe4728a41388be44cd707e0d1e6,

title = "Dehydrogenative Silylation of 1,5-Dienes with Hydrosilanes Catalyzed by RhCl(PPh3)3",

abstract = "The reaction of 1,5-dienes with hydrosilanes using RhCl(PPh3)3 as a catalyst gives 1-silyl-1,5-dienes as the result of dehydrogenative silylation instead of the usual hydrosilylation products.",

author = "Fumitoshi Kakiuchi and Katsuo Nogami and Naoto Chatani and Yoshio Seki and Shinji Murai",

year = "1993",

doi = "10.1021/om00036a013",

language = "English",

volume = "12",

pages = "4748--4750",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Dehydrogenative Silylation of 1,5-Dienes with Hydrosilanes Catalyzed by RhCl(PPh3)3

AU - Kakiuchi, Fumitoshi

AU - Nogami, Katsuo

AU - Chatani, Naoto

AU - Seki, Yoshio

AU - Murai, Shinji

PY - 1993

Y1 - 1993

N2 - The reaction of 1,5-dienes with hydrosilanes using RhCl(PPh3)3 as a catalyst gives 1-silyl-1,5-dienes as the result of dehydrogenative silylation instead of the usual hydrosilylation products.

AB - The reaction of 1,5-dienes with hydrosilanes using RhCl(PPh3)3 as a catalyst gives 1-silyl-1,5-dienes as the result of dehydrogenative silylation instead of the usual hydrosilylation products.

UR - http://www.scopus.com/inward/record.url?scp=0000139787&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000139787&partnerID=8YFLogxK

U2 - 10.1021/om00036a013

DO - 10.1021/om00036a013

M3 - Article

AN - SCOPUS:0000139787

SN - 0276-7333

VL - 12

SP - 4748

EP - 4750

JO - Organometallics

JF - Organometallics

IS - 12

ER -

Dehydrogenative Silylation of 1,5-Dienes with Hydrosilanes Catalyzed by RhCl(PPh₃)₃

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this