Determination of the 13C NMR chemical shifts in an a 2u type iron(III) porphyrin cation radical

Akito Hoshino; Mikio Nakamura

doi:10.1039/b413902j

Determination of the ¹³C NMR chemical shifts in an a _2u type iron(III) porphyrin cation radical

Akito Hoshino, Mikio Nakamura

Department of Radiology

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The ¹³C NMR chemical shifts of all the carbons in an a _2u type iron(III) porphyrin radical cation, [Fe(TPP)Cl]⁺, have been determined for the first time by the titration method as well as by the chemical shift correlation; they are 2230, 1050, and -1910 ppm for the α-pyrrole, β-pyrrole, and meso carbon atoms, respectively.

Original language	English
Pages (from-to)	915-917
Number of pages	3
Journal	Chemical Communications
Issue number	7
DOIs	https://doi.org/10.1039/b413902j
Publication status	Published - 2005 Feb 21

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "The 13C NMR chemical shifts of all the carbons in an a 2u type iron(III) porphyrin radical cation, [Fe(TPP)Cl]+, have been determined for the first time by the titration method as well as by the chemical shift correlation; they are 2230, 1050, and -1910 ppm for the α-pyrrole, β-pyrrole, and meso carbon atoms, respectively.",

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AB - The 13C NMR chemical shifts of all the carbons in an a 2u type iron(III) porphyrin radical cation, [Fe(TPP)Cl]+, have been determined for the first time by the titration method as well as by the chemical shift correlation; they are 2230, 1050, and -1910 ppm for the α-pyrrole, β-pyrrole, and meso carbon atoms, respectively.

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Determination of the ¹³C NMR chemical shifts in an a _2u type iron(III) porphyrin cation radical

Abstract

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