Diaqua[(1R,2R)-N,N′-bis(3,5-dibromosalicylidene)-cyclohexane-1, 2-diamine-κ4O,N,N′,O′]manganese(III) perchlorate dihydrate

Takashiro Akitsu; Yuiri Takeuchi; Yasuaki Einaga

doi:10.1107/S1600536805009062

Diaqua[(1R,2R)-N,N′-bis(3,5-dibromosalicylidene)-cyclohexane-1, 2-diamine-κ⁴O,N,N′,O′]manganese(III) perchlorate dihydrate

Takashiro Akitsu, Yuiri Takeuchi, Yasuaki Einaga

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The crystal structure of the title compound, [Mn(C₂₀H ₁₆Br₄N₂O₂)(H₂O) ₂](ClO₄)·2H₂O, has been determined. The mononuclear complex affords an elongated octahedral MnN₂O ₄ coordination geometry with the four donor atoms of the tetradentate chiral Schiff base in the equatorial plane and with two aqua ligands in axial positions with Mn-O = 2.278 (9) and 2.269 (10) Å.

Original language	English
Pages (from-to)	m772-m774
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	4
DOIs	https://doi.org/10.1107/S1600536805009062
Publication status	Published - 2005 Apr

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Diaqua[(1R,2R)-N,N′-bis(3,5-dibromosalicylidene)-cyclohexane-1, 2-diamine-κ4O,N,N′,O′]manganese(III) perchlorate dihydrate",

abstract = "The crystal structure of the title compound, [Mn(C20H 16Br4N2O2)(H2O) 2](ClO4)·2H2O, has been determined. The mononuclear complex affords an elongated octahedral MnN2O 4 coordination geometry with the four donor atoms of the tetradentate chiral Schiff base in the equatorial plane and with two aqua ligands in axial positions with Mn-O = 2.278 (9) and 2.269 (10) {\AA}.",

author = "Takashiro Akitsu and Yuiri Takeuchi and Yasuaki Einaga",

year = "2005",

month = apr,

doi = "10.1107/S1600536805009062",

language = "English",

volume = "61",

pages = "m772--m774",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "4",

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TY - JOUR

T1 - Diaqua[(1R,2R)-N,N′-bis(3,5-dibromosalicylidene)-cyclohexane-1, 2-diamine-κ4O,N,N′,O′]manganese(III) perchlorate dihydrate

AU - Akitsu, Takashiro

AU - Takeuchi, Yuiri

AU - Einaga, Yasuaki

PY - 2005/4

Y1 - 2005/4

N2 - The crystal structure of the title compound, [Mn(C20H 16Br4N2O2)(H2O) 2](ClO4)·2H2O, has been determined. The mononuclear complex affords an elongated octahedral MnN2O 4 coordination geometry with the four donor atoms of the tetradentate chiral Schiff base in the equatorial plane and with two aqua ligands in axial positions with Mn-O = 2.278 (9) and 2.269 (10) Å.

AB - The crystal structure of the title compound, [Mn(C20H 16Br4N2O2)(H2O) 2](ClO4)·2H2O, has been determined. The mononuclear complex affords an elongated octahedral MnN2O 4 coordination geometry with the four donor atoms of the tetradentate chiral Schiff base in the equatorial plane and with two aqua ligands in axial positions with Mn-O = 2.278 (9) and 2.269 (10) Å.

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U2 - 10.1107/S1600536805009062

DO - 10.1107/S1600536805009062

M3 - Article

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SP - m772-m774

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Diaqua[(1R,2R)-N,N′-bis(3,5-dibromosalicylidene)-cyclohexane-1, 2-diamine-κ⁴O,N,N′,O′]manganese(III) perchlorate dihydrate

Abstract

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