Direct observation of conformers caused by the difference in ligand orientation in low spin iron(III) porphyrin complex

Takahisa Ikeue; Tatsuya Yamaguchi; Yoshiki Ohgo; Mikio Nakamura

doi:10.1246/cl.2000.342

Direct observation of conformers caused by the difference in ligand orientation in low spin iron(III) porphyrin complex

Takahisa Ikeue, Tatsuya Yamaguchi, Yoshiki Ohgo, Mikio Nakamura

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

EPR spectrum of low spin bis(dimethylaminopyridine)(3,8, 13,18-tetramesityl-2,7,12,17-tetramethylporphyrinato)iron(III) perchlorate taken in frozen CH₂Cl₂ solution at 4.2 K showed both large g_max and rhombic type signals. The result has been explained in terms of the presence of two conformers where the dihedral angles between two ligands are different.

Original language	English
Pages (from-to)	342-343
Number of pages	2
Journal	Chemistry Letters
Issue number	4
DOIs	https://doi.org/10.1246/cl.2000.342
Publication status	Published - 2000
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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abstract = "EPR spectrum of low spin bis(dimethylaminopyridine)(3,8, 13,18-tetramesityl-2,7,12,17-tetramethylporphyrinato)iron(III) perchlorate taken in frozen CH2Cl2 solution at 4.2 K showed both large gmax and rhombic type signals. The result has been explained in terms of the presence of two conformers where the dihedral angles between two ligands are different.",

author = "Takahisa Ikeue and Tatsuya Yamaguchi and Yoshiki Ohgo and Mikio Nakamura",

year = "2000",

doi = "10.1246/cl.2000.342",

language = "English",

pages = "342--343",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

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T1 - Direct observation of conformers caused by the difference in ligand orientation in low spin iron(III) porphyrin complex

AU - Ikeue, Takahisa

AU - Yamaguchi, Tatsuya

AU - Ohgo, Yoshiki

AU - Nakamura, Mikio

PY - 2000

Y1 - 2000

N2 - EPR spectrum of low spin bis(dimethylaminopyridine)(3,8, 13,18-tetramesityl-2,7,12,17-tetramethylporphyrinato)iron(III) perchlorate taken in frozen CH2Cl2 solution at 4.2 K showed both large gmax and rhombic type signals. The result has been explained in terms of the presence of two conformers where the dihedral angles between two ligands are different.

AB - EPR spectrum of low spin bis(dimethylaminopyridine)(3,8, 13,18-tetramesityl-2,7,12,17-tetramethylporphyrinato)iron(III) perchlorate taken in frozen CH2Cl2 solution at 4.2 K showed both large gmax and rhombic type signals. The result has been explained in terms of the presence of two conformers where the dihedral angles between two ligands are different.

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 4

ER -

Direct observation of conformers caused by the difference in ligand orientation in low spin iron(III) porphyrin complex

Abstract

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