Abstract
In the direct synthesis of phenylchlorogermanes, copper(I) chloride was the best catalyst among the metal chlorides tested, the products being diphenyldichlorogermane and phenyltrichlorogermane. The reaction mainly gave diphenyldichlorogermane; however at the beginning of the reaction, phenyltrichlorogermane was afforded by the reaction of chlorobenzene and dichlorogermylene formed from metallic germanium and chloride ion in the catalyst.
| Original language | English |
|---|---|
| Pages (from-to) | 33-36 |
| Number of pages | 4 |
| Journal | Catalysis Letters |
| Volume | 78 |
| Issue number | 1-4 |
| DOIs | |
| Publication status | Published - 2002 Mar |
| Externally published | Yes |
Keywords
- Copper catalyst
- Direct synthesis
- Metallic germanium
- Phenylchlorogermane
- Silver catalyst
ASJC Scopus subject areas
- Catalysis
- General Chemistry
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