Electrical conductivity modulation coupled to a high-spin-low-spin conversion in the molecular system [FeIII(qsal)2][Ni(dmit) 2]3·CH3CN·H2O

Kazuyuki Takahashi; Heng Bo Cui; Yoshinori Okano; Hayao Kobayashi; Yasuaki Einaga; Osamu Sato

doi:10.1021/ic060852l

Electrical conductivity modulation coupled to a high-spin-low-spin conversion in the molecular system [Fe^III(qsal)₂][Ni(dmit) ₂]₃·CH₃CN·H₂O

Kazuyuki Takahashi, Heng Bo Cui, Yoshinori Okano, Hayao Kobayashi, Yasuaki Einaga, Osamu Sato

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

127 Citations (Scopus)

Abstract

The synergy between the electrical conductivity within the stacks of Ni(dmit)₂ in the newly electrocrystallized [Fe(qsal) ₂][Ni(dmit)₂]₃· CH₃CN· H₂O and the spin conversion of Fe(qsal)₂ is evidenced. In addition, the presence of a light-induced excited spin state trapping effect suggests that this complex is a prototypal photoswitchable spin-crossover molecular conductor.

Original language	English
Pages (from-to)	5739-5741
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	15
DOIs	https://doi.org/10.1021/ic060852l
Publication status	Published - 2006 Jul 24

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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abstract = "The synergy between the electrical conductivity within the stacks of Ni(dmit)2 in the newly electrocrystallized [Fe(qsal) 2][Ni(dmit)2]3· CH3CN· H2O and the spin conversion of Fe(qsal)2 is evidenced. In addition, the presence of a light-induced excited spin state trapping effect suggests that this complex is a prototypal photoswitchable spin-crossover molecular conductor.",

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AU - Takahashi, Kazuyuki

AU - Cui, Heng Bo

AU - Okano, Yoshinori

AU - Kobayashi, Hayao

AU - Einaga, Yasuaki

AU - Sato, Osamu

PY - 2006/7/24

Y1 - 2006/7/24

N2 - The synergy between the electrical conductivity within the stacks of Ni(dmit)2 in the newly electrocrystallized [Fe(qsal) 2][Ni(dmit)2]3· CH3CN· H2O and the spin conversion of Fe(qsal)2 is evidenced. In addition, the presence of a light-induced excited spin state trapping effect suggests that this complex is a prototypal photoswitchable spin-crossover molecular conductor.

AB - The synergy between the electrical conductivity within the stacks of Ni(dmit)2 in the newly electrocrystallized [Fe(qsal) 2][Ni(dmit)2]3· CH3CN· H2O and the spin conversion of Fe(qsal)2 is evidenced. In addition, the presence of a light-induced excited spin state trapping effect suggests that this complex is a prototypal photoswitchable spin-crossover molecular conductor.

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Electrical conductivity modulation coupled to a high-spin-low-spin conversion in the molecular system [Fe^III(qsal)₂][Ni(dmit) ₂]₃·CH₃CN·H₂O

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