Electroreduction of CO2 using copper-deposited on boron-doped diamond (BDD)

Hanum Sekar Panglipur; Tribidasari A. Ivandini; Rahmat Wibowo; Yasuaki Einaga

doi:10.1063/1.4946950

Electroreduction of CO₂ using copper-deposited on boron-doped diamond (BDD)

Hanum Sekar Panglipur, Tribidasari A. Ivandini, Rahmat Wibowo, Yasuaki Einaga

Department of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

12 Citations (Scopus)

Abstract

Electroreduction of CO₂ was studied at copper-modified boron-doped diamond (Cu-BDD) electrodes as the working electrode. The Cu-BDD electrodes were prepared by electrochemical reduction with various concentrations of CuSO₄ solutions. FE-SEM was utilized to characterize the electrodes. At Cu-BDD electrodes, a reduction peak at around-1.2 V (vs Ag/AgCl) attributtable to CO₂ reductions could be observed by cyclic voltammetry technique of CO₂ bubbled in water containing 0.1M NaCl. Accordingly, electroreduction of CO₂ was conducted at-1.2 V (vs Ag/AgCl) using amperometry technique. The chemical products of the electroreduction analyzed by using HPLC showed the formation of formaldehyde, formic acid, and acetic acid at Cu-BDD electrodes.

Original language	English
Title of host publication	International Symposium on Current Progress in Mathematics and Sciences 2015, ISCPMS 2015
Subtitle of host publication	Proceedings of the 1st International Symposium on Current Progress in Mathematics and Sciences
Editors	Terry Mart, Djoko Triyono
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735413764
DOIs	https://doi.org/10.1063/1.4946950
Publication status	Published - 2016 Apr 19
Event	1st International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2015 - Depok, Indonesia Duration: 2015 Nov 3 → 2015 Nov 4

Publication series

Name	AIP Conference Proceedings
Volume	1729
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Other

Other	1st International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2015
Country/Territory	Indonesia
City	Depok
Period	15/11/3 → 15/11/4

ASJC Scopus subject areas

Physics and Astronomy(all)

Access to Document

10.1063/1.4946950

Cite this

Panglipur, H. S., Ivandini, T. A., Wibowo, R., & Einaga, Y. (2016). Electroreduction of CO₂ using copper-deposited on boron-doped diamond (BDD). In T. Mart, & D. Triyono (Eds.), International Symposium on Current Progress in Mathematics and Sciences 2015, ISCPMS 2015: Proceedings of the 1st International Symposium on Current Progress in Mathematics and Sciences Article 020047 (AIP Conference Proceedings; Vol. 1729). American Institute of Physics Inc.. https://doi.org/10.1063/1.4946950

Electroreduction of CO₂ using copper-deposited on boron-doped diamond (BDD). / Panglipur, Hanum Sekar; Ivandini, Tribidasari A.; Wibowo, Rahmat et al.
International Symposium on Current Progress in Mathematics and Sciences 2015, ISCPMS 2015: Proceedings of the 1st International Symposium on Current Progress in Mathematics and Sciences. ed. / Terry Mart; Djoko Triyono. American Institute of Physics Inc., 2016. 020047 (AIP Conference Proceedings; Vol. 1729).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Panglipur, HS, Ivandini, TA, Wibowo, R & Einaga, Y 2016, Electroreduction of CO₂ using copper-deposited on boron-doped diamond (BDD). in T Mart & D Triyono (eds), International Symposium on Current Progress in Mathematics and Sciences 2015, ISCPMS 2015: Proceedings of the 1st International Symposium on Current Progress in Mathematics and Sciences., 020047, AIP Conference Proceedings, vol. 1729, American Institute of Physics Inc., 1st International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2015, Depok, Indonesia, 15/11/3. https://doi.org/10.1063/1.4946950

Panglipur HS, Ivandini TA, Wibowo R, Einaga Y. Electroreduction of CO₂ using copper-deposited on boron-doped diamond (BDD). In Mart T, Triyono D, editors, International Symposium on Current Progress in Mathematics and Sciences 2015, ISCPMS 2015: Proceedings of the 1st International Symposium on Current Progress in Mathematics and Sciences. American Institute of Physics Inc. 2016. 020047. (AIP Conference Proceedings). doi: 10.1063/1.4946950

Panglipur, Hanum Sekar ; Ivandini, Tribidasari A. ; Wibowo, Rahmat et al. / Electroreduction of CO₂ using copper-deposited on boron-doped diamond (BDD). International Symposium on Current Progress in Mathematics and Sciences 2015, ISCPMS 2015: Proceedings of the 1st International Symposium on Current Progress in Mathematics and Sciences. editor / Terry Mart ; Djoko Triyono. American Institute of Physics Inc., 2016. (AIP Conference Proceedings).

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AB - Electroreduction of CO2 was studied at copper-modified boron-doped diamond (Cu-BDD) electrodes as the working electrode. The Cu-BDD electrodes were prepared by electrochemical reduction with various concentrations of CuSO4 solutions. FE-SEM was utilized to characterize the electrodes. At Cu-BDD electrodes, a reduction peak at around-1.2 V (vs Ag/AgCl) attributtable to CO2 reductions could be observed by cyclic voltammetry technique of CO2 bubbled in water containing 0.1M NaCl. Accordingly, electroreduction of CO2 was conducted at-1.2 V (vs Ag/AgCl) using amperometry technique. The chemical products of the electroreduction analyzed by using HPLC showed the formation of formaldehyde, formic acid, and acetic acid at Cu-BDD electrodes.

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