Enantioselective CO2 fixation catalyzed by optically active cobalt complexes

Hirotaka Tanaka; Yasunori Kitaichi; Mitsuo Sato; Taketo Ikeno; Tohru Yamada

doi:10.1246/cl.2004.676

Enantioselective CO₂ fixation catalyzed by optically active cobalt complexes

Hirotaka Tanaka, Yasunori Kitaichi, Mitsuo Sato, Taketo Ikeno, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

In the presence of a catalytic amount of optically active cobalt complexes and amine bases, a racemic epoxide, such as N,N-diphenylaminomethyloxirane, reacted with gaseous carbon dioxide to afford the optically active cyclic carbonate along with the optically active starting epoxide.

Original language	English
Pages (from-to)	676-677
Number of pages	2
Journal	Chemistry Letters
Volume	33
Issue number	6
DOIs	https://doi.org/10.1246/cl.2004.676
Publication status	Published - 2004 Jun 5

ASJC Scopus subject areas

General Chemistry

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10.1246/cl.2004.676

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title = "Enantioselective CO2 fixation catalyzed by optically active cobalt complexes",

abstract = "In the presence of a catalytic amount of optically active cobalt complexes and amine bases, a racemic epoxide, such as N,N-diphenylaminomethyloxirane, reacted with gaseous carbon dioxide to afford the optically active cyclic carbonate along with the optically active starting epoxide.",

author = "Hirotaka Tanaka and Yasunori Kitaichi and Mitsuo Sato and Taketo Ikeno and Tohru Yamada",

year = "2004",

month = jun,

day = "5",

doi = "10.1246/cl.2004.676",

language = "English",

volume = "33",

pages = "676--677",

journal = "Chemistry Letters",

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publisher = "Chemical Society of Japan",

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T1 - Enantioselective CO2 fixation catalyzed by optically active cobalt complexes

AU - Tanaka, Hirotaka

AU - Kitaichi, Yasunori

AU - Sato, Mitsuo

AU - Ikeno, Taketo

AU - Yamada, Tohru

PY - 2004/6/5

Y1 - 2004/6/5

N2 - In the presence of a catalytic amount of optically active cobalt complexes and amine bases, a racemic epoxide, such as N,N-diphenylaminomethyloxirane, reacted with gaseous carbon dioxide to afford the optically active cyclic carbonate along with the optically active starting epoxide.

AB - In the presence of a catalytic amount of optically active cobalt complexes and amine bases, a racemic epoxide, such as N,N-diphenylaminomethyloxirane, reacted with gaseous carbon dioxide to afford the optically active cyclic carbonate along with the optically active starting epoxide.

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U2 - 10.1246/cl.2004.676

DO - 10.1246/cl.2004.676

M3 - Article

AN - SCOPUS:4444342733

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VL - 33

SP - 676

EP - 677

JO - Chemistry Letters

JF - Chemistry Letters

IS - 6

ER -

Enantioselective CO₂ fixation catalyzed by optically active cobalt complexes

Abstract

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