Endo-selective asymmetric inverse electron-demand 1,3-dipolar cycloaddition reaction of nitrones

Tomoko Ashizawa; Natsuki Ohtsuki; Tomoyuki Miura; Makoto Ohya; Takaomi Shinozaki; Taketo Ikeno; Tohru Yamada

doi:10.3987/COM-06-10791

Endo-selective asymmetric inverse electron-demand 1,3-dipolar cycloaddition reaction of nitrones

Tomoko Ashizawa, Natsuki Ohtsuki, Tomoyuki Miura, Makoto Ohya, Takaomi Shinozaki, Taketo Ikeno, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

In the presence of a catalytic amount of the optically active cobalt(III) hexafluoroantimonate, the inverse electron-demand 1,3-dipolar cycloaddition reaction of dihydrofuran with nitrones bearing an electron-withdrawing group effectively proceeded to afford the corresponding adducts with excellent endo-selectivity.{A figure is presented}.

Original language	English
Pages (from-to)	1801-1810
Number of pages	10
Journal	Heterocycles
Volume	68
Issue number	9
DOIs	https://doi.org/10.3987/COM-06-10791
Publication status	Published - 2006 Sept 1

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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title = "Endo-selective asymmetric inverse electron-demand 1,3-dipolar cycloaddition reaction of nitrones",

abstract = "In the presence of a catalytic amount of the optically active cobalt(III) hexafluoroantimonate, the inverse electron-demand 1,3-dipolar cycloaddition reaction of dihydrofuran with nitrones bearing an electron-withdrawing group effectively proceeded to afford the corresponding adducts with excellent endo-selectivity.{A figure is presented}.",

author = "Tomoko Ashizawa and Natsuki Ohtsuki and Tomoyuki Miura and Makoto Ohya and Takaomi Shinozaki and Taketo Ikeno and Tohru Yamada",

year = "2006",

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doi = "10.3987/COM-06-10791",

language = "English",

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publisher = "Japan Institute of Heterocyclic Chemistry",

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T1 - Endo-selective asymmetric inverse electron-demand 1,3-dipolar cycloaddition reaction of nitrones

AU - Ashizawa, Tomoko

AU - Ohtsuki, Natsuki

AU - Miura, Tomoyuki

AU - Ohya, Makoto

AU - Shinozaki, Takaomi

AU - Ikeno, Taketo

AU - Yamada, Tohru

PY - 2006/9/1

Y1 - 2006/9/1

N2 - In the presence of a catalytic amount of the optically active cobalt(III) hexafluoroantimonate, the inverse electron-demand 1,3-dipolar cycloaddition reaction of dihydrofuran with nitrones bearing an electron-withdrawing group effectively proceeded to afford the corresponding adducts with excellent endo-selectivity.{A figure is presented}.

AB - In the presence of a catalytic amount of the optically active cobalt(III) hexafluoroantimonate, the inverse electron-demand 1,3-dipolar cycloaddition reaction of dihydrofuran with nitrones bearing an electron-withdrawing group effectively proceeded to afford the corresponding adducts with excellent endo-selectivity.{A figure is presented}.

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DO - 10.3987/COM-06-10791

M3 - Article

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JO - Heterocycles

JF - Heterocycles

IS - 9

ER -

Endo-selective asymmetric inverse electron-demand 1,3-dipolar cycloaddition reaction of nitrones

Abstract

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