Environmentally benign and stereoselective formation of β-mannosidic linkages utilizing 2,3-di-O-benzyl-4,6-O-benzylidene-protected mannopyranosyl phosphite and montmorillonite K-10

Hideyuki Nagai; Shuichi Matsumura; Kazunobu Toshima

doi:10.1016/S0008-6215(03)00234-9

Environmentally benign and stereoselective formation of β-mannosidic linkages utilizing 2,3-di-O-benzyl-4,6-O-benzylidene-protected mannopyranosyl phosphite and montmorillonite K-10

Hideyuki Nagai, Shuichi Matsumura, Kazunobu Toshima

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

An environmentally benign and stereoselective β-mannopyranosylation has been developed employing 4,6-O-benzylidene-protected mannopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.

Original language	English
Pages (from-to)	1531-1534
Number of pages	4
Journal	Carbohydrate Research
Volume	338
Issue number	15
DOIs	https://doi.org/10.1016/S0008-6215(03)00234-9
Publication status	Published - 2003 Jul 22

Keywords

Glycosidation
Glycosyl phosphite
Montmorillonite K-10
Solid acid
β-Mannopyranoside

ASJC Scopus subject areas

Analytical Chemistry
Biochemistry
Organic Chemistry

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10.1016/S0008-6215(03)00234-9

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Environmentally benign and stereoselective formation of β-mannosidic linkages utilizing 2,3-di-O-benzyl-4,6-O-benzylidene-protected mannopyranosyl phosphite and montmorillonite K-10. / Nagai, Hideyuki; Matsumura, Shuichi; Toshima, Kazunobu.
In: Carbohydrate Research, Vol. 338, No. 15, 22.07.2003, p. 1531-1534.

Research output: Contribution to journal › Article › peer-review

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abstract = "An environmentally benign and stereoselective β-mannopyranosylation has been developed employing 4,6-O-benzylidene-protected mannopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.",

keywords = "Glycosidation, Glycosyl phosphite, Montmorillonite K-10, Solid acid, β-Mannopyranoside",

author = "Hideyuki Nagai and Shuichi Matsumura and Kazunobu Toshima",

note = "Funding Information: This research was partially supported by Grant-in-Aid for the 21st Century COE program {\textquoteleft}KEIO Life Conjugate Chemistry{\textquoteright} from the Ministry of Education, Culture, Sports, Science, and Technology, Japan.",

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AU - Nagai, Hideyuki

AU - Matsumura, Shuichi

AU - Toshima, Kazunobu

N1 - Funding Information: This research was partially supported by Grant-in-Aid for the 21st Century COE program ‘KEIO Life Conjugate Chemistry’ from the Ministry of Education, Culture, Sports, Science, and Technology, Japan.

PY - 2003/7/22

Y1 - 2003/7/22

N2 - An environmentally benign and stereoselective β-mannopyranosylation has been developed employing 4,6-O-benzylidene-protected mannopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.

AB - An environmentally benign and stereoselective β-mannopyranosylation has been developed employing 4,6-O-benzylidene-protected mannopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.

KW - Glycosidation

KW - Glycosyl phosphite

KW - Montmorillonite K-10

KW - Solid acid

KW - β-Mannopyranoside

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JO - Carbohydrate Research

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Environmentally benign and stereoselective formation of β-mannosidic linkages utilizing 2,3-di-O-benzyl-4,6-O-benzylidene-protected mannopyranosyl phosphite and montmorillonite K-10

Abstract

Keywords

ASJC Scopus subject areas

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