Failure of deterministic and stochastic thermostats to control temperature of molecular systems

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Abstract

We investigate the ergodicity and “hot solvent=cold solute” problems in molecular dynamics simulations. While the kinetic moments and the stimulated Nosé–Hoover methods improve the ergodicity of a harmonic-oscillator system, both methods exhibit the “hot solvent=cold solute” problem in a binary liquid system. These results show that the devices to improve the ergodicity do not resolve the “hot solvent=cold solute” problem.

Original languageEnglish
Article number075004
JournalJournal of the Physical Society of Japan
Volume86
Issue number7
DOIs
Publication statusPublished - 2017 Jul 15
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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