Formation and characterization of a six-coordinate iron(iii) complex with the most ruffled porphyrin ring

Akira Ikezaki; Mikio Nakamura

doi:10.1039/c1dt10042d

Formation and characterization of a six-coordinate iron(iii) complex with the most ruffled porphyrin ring

Akira Ikezaki, Mikio Nakamura

Department of Radiology

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The six-coordinate iron(iii) porphyrin complex, [Fe(TⁱPrP)(2- MeBzIm)₂]⁺, having the most ruffled porphyrin ring shows some unusual properties; the complex adopts the pure (d_xz, d _yz)⁴(d_xy)¹ ground state below 200 K in spite of the coordination of an imidazole ligand and exhibits the rare spin transition to the (d_xz, d_yz)³(d _xy)¹(d_z2)¹ state at higher temperature.

Original language	English
Pages (from-to)	3455-3458
Number of pages	4
Journal	Dalton Transactions
Volume	40
Issue number	14
DOIs	https://doi.org/10.1039/c1dt10042d
Publication status	Published - 2011

ASJC Scopus subject areas

Inorganic Chemistry

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abstract = "The six-coordinate iron(iii) porphyrin complex, [Fe(TiPrP)(2- MeBzIm)2]+, having the most ruffled porphyrin ring shows some unusual properties; the complex adopts the pure (dxz, d yz)4(dxy)1 ground state below 200 K in spite of the coordination of an imidazole ligand and exhibits the rare spin transition to the (dxz, dyz)3(d xy)1(dz2)1 state at higher temperature.",

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AU - Nakamura, Mikio

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AB - The six-coordinate iron(iii) porphyrin complex, [Fe(TiPrP)(2- MeBzIm)2]+, having the most ruffled porphyrin ring shows some unusual properties; the complex adopts the pure (dxz, d yz)4(dxy)1 ground state below 200 K in spite of the coordination of an imidazole ligand and exhibits the rare spin transition to the (dxz, dyz)3(d xy)1(dz2)1 state at higher temperature.

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Formation and characterization of a six-coordinate iron(iii) complex with the most ruffled porphyrin ring

Abstract

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