Glycosidation of glycals by 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) as a catalytic promoter

Kazunobu Toshima, Toru Ishizuka, Goh Matsuo, Masaya Nakata, Mitsuhiro Kinoshita

Research output: Contribution to journalArticlepeer-review

90 Citations (Scopus)

Abstract

O-Glycosidations of glycals 1, 8 and 9 with several alcohols by using a catalytic amount of 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) under neutral conditions proceeds smoothly to give the corresponding 2,3-unsaturated glycosides in high yields.

Original languageEnglish
Pages (from-to)704-706
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number8
DOIs
Publication statusPublished - 1993

ASJC Scopus subject areas

  • Molecular Medicine

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