@article{4c578e7596184af2a93a3363a17a7c20,
title = "Gold(i)-catalyzed Nicholas reaction with aromatic molecules utilizing a bifunctional propargyl dicobalt hexacarbonyl complex",
abstract = "A benchtop-stable reagent for the catalytic Nicholas reaction was developed. By combining a propargyl dicobalt hexacarbonyl cluster with an ortho-alkynylbenzoate unit and a fluorous tag, introduction of a propargyl hexacarbonyl complex on various aromatic compounds having acid- or base-sensitive functional groups becomes possible by using a gold(i) catalyst. In addition, the presence of a fluorous tag facilitates convenient separation of the target products from byproducts.",
author = "Toshitaka Okamura and Shogo Fujiki and Yoshiharu Iwabuchi and Naoki Kanoh",
note = "Funding Information: This work was partially supported by The Naito Foundation, by a Grant-in-Aid for Scientific Research on the Innovative Area “Chemical Biology of Natural Products” (No. 23102013 to NK) and “Frontier Research on Chemical Communications” (No. 18H04603) from The Ministry of Education, Culture, Sports, Science, and Technology of Japan, by the Platform Project for Supporting Drug Discovery and Life Science Research (Platform for Drug Discovery, Informatics, and Structural Life Science) (No. JP18am0101100) from the Japan Agency for Medical Research and Development (AMED), and by a Grant-in-Aid for JSPS fellows (No. 172575 to T. O.) from the Japan Society for the Promotion of Science (JSPS). Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",
year = "2019",
doi = "10.1039/c9ob01348b",
language = "English",
volume = "17",
pages = "8522--8526",
journal = "Organic and Biomolecular Chemistry",
issn = "1477-0520",
publisher = "Royal Society of Chemistry",
number = "37",
}