Abstract
The cooperative surface-catalysis strategy of a Brønsted acid and an organic base can be extended to a metal complex and organic base pair. A silica-supported diaminopalladium complex and a tertiary amine were prepared and characterized. The Pd-catalyzed Tsuji-Trost reaction was enhanced significantly by the presence of the tertiary amine on the same silica surface as the Pd complex.
| Original language | English |
|---|---|
| Pages (from-to) | 8017-8020 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 51 |
| Issue number | 32 |
| DOIs | |
| Publication status | Published - 2012 Aug 6 |
| Externally published | Yes |
Keywords
- amines
- heterogeneous catalysis
- palladium
- supported catalysis
- Tsuji-Trost reaction
ASJC Scopus subject areas
- Catalysis
- General Chemistry
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