Highly ruffled manganese(III) complexes of meso-tetra(tert-butyl)porphyrin

Akira Ikezaki; Mikio Nakamura

doi:10.1246/cl.2005.1046

Highly ruffled manganese(III) complexes of meso-tetra(tert-butyl)porphyrin

Akira Ikezaki, Mikio Nakamura

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7 Citations (Scopus)

Abstract

Extraordinarily ruffled acetato[5,10,15,20-tetra(tert-butyl)-porphinato] manganese(III) has been prepared. The ¹H NMR spectra have revealed that the inversion barrier of the porphyrin ring exceeds 66 kJ mol^-1 and that the spin densities are quite different between the diastereotopic β-carbon atoms.

Original language	English
Pages (from-to)	1046-1047
Number of pages	2
Journal	Chemistry Letters
Volume	34
Issue number	7
DOIs	https://doi.org/10.1246/cl.2005.1046
Publication status	Published - 2005 Jul 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2005.1046

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abstract = "Extraordinarily ruffled acetato[5,10,15,20-tetra(tert-butyl)-porphinato] manganese(III) has been prepared. The 1H NMR spectra have revealed that the inversion barrier of the porphyrin ring exceeds 66 kJ mol-1 and that the spin densities are quite different between the diastereotopic β-carbon atoms.",

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N2 - Extraordinarily ruffled acetato[5,10,15,20-tetra(tert-butyl)-porphinato] manganese(III) has been prepared. The 1H NMR spectra have revealed that the inversion barrier of the porphyrin ring exceeds 66 kJ mol-1 and that the spin densities are quite different between the diastereotopic β-carbon atoms.

AB - Extraordinarily ruffled acetato[5,10,15,20-tetra(tert-butyl)-porphinato] manganese(III) has been prepared. The 1H NMR spectra have revealed that the inversion barrier of the porphyrin ring exceeds 66 kJ mol-1 and that the spin densities are quite different between the diastereotopic β-carbon atoms.

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Highly ruffled manganese(III) complexes of meso-tetra(tert-butyl)porphyrin

Abstract

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