Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer

Masaaki Mitsui; Shingo Doi; Kaori Ikemoto; Shuhei Nagaoka; Atsushi Nakajima

doi:10.1142/9781848162389_0016

Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer

Masaaki Mitsui, Shingo Doi, Kaori Ikemoto, Shuhei Nagaoka, Atsushi Nakajima

Department of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

Gas-phase synthesized vanadium-mesitylene 1:2 V(mes)₂ cluster cations were size-selectively deposited onto a long-chain alkanethiolate selfassembled monolayer-coated gold substrate under ultrahigh vacuum conditions. Examination of the resultant clusters was conducted by infrared reflection absorption spectroscopy (IRAS) and temperature programmed desorption (TPD), showing the clusters molecularly adsorbed and maintaining a sandwich structure on the substrate.

Original language	English
Title of host publication	Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale
Publisher	Imperial College Press
Pages	199-204
Number of pages	6
ISBN (Print)	9781848162389, 9781848162372
DOIs	https://doi.org/10.1142/9781848162389_0016
Publication status	Published - 2008 Jan 1

Keywords

Cluster
Self-assembled monolayer
Soft-landing

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)
Chemistry(all)
Physics and Astronomy(all)

Access to Document

10.1142/9781848162389_0016

Cite this

Mitsui, M., Doi, S., Ikemoto, K., Nagaoka, S., & Nakajima, A. (2008). Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer. In Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale (pp. 199-204). Imperial College Press. https://doi.org/10.1142/9781848162389_0016

Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer. / Mitsui, Masaaki; Doi, Shingo; Ikemoto, Kaori et al.
Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale. Imperial College Press, 2008. p. 199-204.

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Mitsui, M, Doi, S, Ikemoto, K, Nagaoka, S & Nakajima, A 2008, Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer. in Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale. Imperial College Press, pp. 199-204. https://doi.org/10.1142/9781848162389_0016

Mitsui M, Doi S, Ikemoto K, Nagaoka S, Nakajima A. Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer. In Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale. Imperial College Press. 2008. p. 199-204 doi: 10.1142/9781848162389_0016

Mitsui, Masaaki ; Doi, Shingo ; Ikemoto, Kaori et al. / Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1 : 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer. Latest Advances in Atomic Cluster Collisions: Structure and Dynamics from the Nuclear to the Biological Scale. Imperial College Press, 2008. pp. 199-204

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Infrared spectroscopy and thermal desorption study of vanadium–mesitylene 1: 2 sandwich clusters soft-landed onto a long-chain N-alkanethiolate self-assembled monolayer

Abstract

Keywords

ASJC Scopus subject areas

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