Intramolecular reaction of electrogenerated phenoxy cations with an olefin bearing an electron-releasing group at the side chain

Shojiro Maki; Toshiyuki Suzuki; Seiji Kosemura; Yoshikazu Shizuri; Shosuke Yamamura

doi:10.1016/S0040-4039(00)93511-1

Intramolecular reaction of electrogenerated phenoxy cations with an olefin bearing an electron-releasing group at the side chain

Shojiro Maki, Toshiyuki Suzuki, Seiji Kosemura, Yoshikazu Shizuri, Shosuke Yamamura

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Some phenols with an olefinic side chain have been electrolyzed under various conditions to afford both intramolecular [5 + 1]cycloaddition products and spiro compounds depending on solvent, substituents on the olefinic double bond and others. These rection products are regarded as a synthetic key intermediate of bioactive terpenoids.

Original language	English
Pages (from-to)	4973-4976
Number of pages	4
Journal	Tetrahedron Letters
Volume	32
Issue number	37
DOIs	https://doi.org/10.1016/S0040-4039(00)93511-1
Publication status	Published - 1991 Sept 9
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)93511-1

Cite this

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abstract = "Some phenols with an olefinic side chain have been electrolyzed under various conditions to afford both intramolecular [5 + 1]cycloaddition products and spiro compounds depending on solvent, substituents on the olefinic double bond and others. These rection products are regarded as a synthetic key intermediate of bioactive terpenoids.",

author = "Shojiro Maki and Toshiyuki Suzuki and Seiji Kosemura and Yoshikazu Shizuri and Shosuke Yamamura",

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T1 - Intramolecular reaction of electrogenerated phenoxy cations with an olefin bearing an electron-releasing group at the side chain

AU - Maki, Shojiro

AU - Suzuki, Toshiyuki

AU - Kosemura, Seiji

AU - Shizuri, Yoshikazu

AU - Yamamura, Shosuke

N1 - Funding Information: This research has been supported in parts by grants from the Ministry of Education, Science and Culture as

PY - 1991/9/9

Y1 - 1991/9/9

N2 - Some phenols with an olefinic side chain have been electrolyzed under various conditions to afford both intramolecular [5 + 1]cycloaddition products and spiro compounds depending on solvent, substituents on the olefinic double bond and others. These rection products are regarded as a synthetic key intermediate of bioactive terpenoids.

AB - Some phenols with an olefinic side chain have been electrolyzed under various conditions to afford both intramolecular [5 + 1]cycloaddition products and spiro compounds depending on solvent, substituents on the olefinic double bond and others. These rection products are regarded as a synthetic key intermediate of bioactive terpenoids.

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U2 - 10.1016/S0040-4039(00)93511-1

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JF - Tetrahedron Letters

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ER -

Intramolecular reaction of electrogenerated phenoxy cations with an olefin bearing an electron-releasing group at the side chain

Abstract

ASJC Scopus subject areas

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