Is cyanide really a strong-field ligand?

Mikio Nakamura

doi:10.1002/anie.200805446

Is cyanide really a strong-field ligand?

Mikio Nakamura

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Iron man or weakling? Ligand-field strengths are conveniently expressed by the empirical spectrochemical series. Although cyanide has been deeply entrenched as a strong-field ligand, a couple of recent examples cast doubt toward the position of this ligand, namely the high-spin (S=2) states of [Cr^II(CN)₅]^3- and [Fe^II(tpp)(CN)] ^-. tpp=meso-tetraphenylporphinate.

Original language	English
Pages (from-to)	2638-2640
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	15
DOIs	https://doi.org/10.1002/anie.200805446
Publication status	Published - 2009 Mar 30
Externally published	Yes

Keywords

Chromium
Crystal-field theory
Cyanide
Iron
Spin states

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200805446

Cite this

@article{99d3bd20f8814260aacd2ae5790c5eb2,

title = "Is cyanide really a strong-field ligand?",

abstract = "Iron man or weakling? Ligand-field strengths are conveniently expressed by the empirical spectrochemical series. Although cyanide has been deeply entrenched as a strong-field ligand, a couple of recent examples cast doubt toward the position of this ligand, namely the high-spin (S=2) states of [CrII(CN)5]3- and [FeII(tpp)(CN)] -. tpp=meso-tetraphenylporphinate.",

keywords = "Chromium, Crystal-field theory, Cyanide, Iron, Spin states",

author = "Mikio Nakamura",

year = "2009",

month = mar,

day = "30",

doi = "10.1002/anie.200805446",

language = "English",

volume = "48",

pages = "2638--2640",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",