TY - JOUR
T1 - Isobaric heat capacity of liquid 1,1,1,3,3-pentafluoropropane (R245fa) by flow calorimeter from 278 K to 343 K
AU - Tanaka, Hiroshi
AU - Fujiwara, Naoki
AU - Sato, Haruki
PY - 2015/12/10
Y1 - 2015/12/10
N2 - Isobaric heat capacity of liquid 1,1,1,3,3-pentafluoropropane (R245fa) was measured. Since our group constructed a flow-calorimeter in 1985, specific isobaric heat capacity of liquid refrigerants have been measured for R32, R123, R125, R134a, R142b, and R152a. In 2014, the authors modified the apparatus of flow calorimetry with an improvement for achieving a stable mass-flow-rate by introducing plastic accumulators and two parallel needle valves. The apparatus is able to measure isobaric heat capacity with unmeasurable level small heat loss and good repeatability mostly within 0.4 % (80 % of the data) and the largest 1.5 % from the maximum scatter. The measurements were obtained at 15 points of state parameters, along two pressures of 500 kPa and 800 kPa in a temperature range from 278 K to 343 K. The expanded uncertainty (coverage factor of k = 2) for the heat capacity value is predicted for each datum as being between 0.36 and 1.12 %. The purity of the sample liquid R245fa is analyzed as being better than 99.99 in mass fraction by the manufacture.
AB - Isobaric heat capacity of liquid 1,1,1,3,3-pentafluoropropane (R245fa) was measured. Since our group constructed a flow-calorimeter in 1985, specific isobaric heat capacity of liquid refrigerants have been measured for R32, R123, R125, R134a, R142b, and R152a. In 2014, the authors modified the apparatus of flow calorimetry with an improvement for achieving a stable mass-flow-rate by introducing plastic accumulators and two parallel needle valves. The apparatus is able to measure isobaric heat capacity with unmeasurable level small heat loss and good repeatability mostly within 0.4 % (80 % of the data) and the largest 1.5 % from the maximum scatter. The measurements were obtained at 15 points of state parameters, along two pressures of 500 kPa and 800 kPa in a temperature range from 278 K to 343 K. The expanded uncertainty (coverage factor of k = 2) for the heat capacity value is predicted for each datum as being between 0.36 and 1.12 %. The purity of the sample liquid R245fa is analyzed as being better than 99.99 in mass fraction by the manufacture.
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U2 - 10.1021/acs.jced.5b00597
DO - 10.1021/acs.jced.5b00597
M3 - Article
AN - SCOPUS:84949650147
SN - 0021-9568
VL - 60
SP - 3594
EP - 3599
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 12
ER -