Lithium insertion behaviour of silver vanadium bronze

Jin Kawakita; Yasushi Katayama; Takashi Miura; Tomiya Kishi

doi:10.1016/s0167-2738(97)00120-3

Lithium insertion behaviour of silver vanadium bronze

Jin Kawakita, Yasushi Katayama, Takashi Miura, Tomiya Kishi

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Ag_1+xV₃O₈ has been prepared by the ion exchange reaction in the molten salt of AgNO₃ using Na_1.2V₃O₈. This oxide has a similar layer structure to M_1+xV₃O₈ (M = Li and Na), and its lattice parameter has been determined. Up to four moles of lithium (x = 4) in Li_xAg_1.2V₃O₈ are accommodated electrochemically. The discharge process showed that after deposition of metallic silver by reduction of Ag(I) prior to V(V) and simultaneous occupation of the octahedral site by inserted Li(I), additional lithium was inserted into Li_1.2V₃O₈. The charging process showed extraction of three lithiums from Li₄V₃O₈ and no return of the silver element back to the original structure with oxidation.

Original language	English
Pages (from-to)	71-78
Number of pages	8
Journal	Solid State Ionics
Volume	99
Issue number	1-2
DOIs	https://doi.org/10.1016/s0167-2738(97)00120-3
Publication status	Published - 1997 Aug 1

Keywords

Insertion
Lithium
Molten salts
Silver
Vanadium

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1016/s0167-2738(97)00120-3

Cite this

@article{b4501dc686fd4d3ba4f987c51ada863f,

title = "Lithium insertion behaviour of silver vanadium bronze",

abstract = "Ag1+xV3O8 has been prepared by the ion exchange reaction in the molten salt of AgNO3 using Na1.2V3O8. This oxide has a similar layer structure to M1+xV3O8 (M = Li and Na), and its lattice parameter has been determined. Up to four moles of lithium (x = 4) in LixAg1.2V3O8 are accommodated electrochemically. The discharge process showed that after deposition of metallic silver by reduction of Ag(I) prior to V(V) and simultaneous occupation of the octahedral site by inserted Li(I), additional lithium was inserted into Li1.2V3O8. The charging process showed extraction of three lithiums from Li4V3O8 and no return of the silver element back to the original structure with oxidation.",

keywords = "Insertion, Lithium, Molten salts, Silver, Vanadium",

author = "Jin Kawakita and Yasushi Katayama and Takashi Miura and Tomiya Kishi",

year = "1997",

month = aug,

day = "1",

doi = "10.1016/s0167-2738(97)00120-3",

language = "English",

volume = "99",

pages = "71--78",

journal = "Solid State Ionics",

issn = "0167-2738",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - Lithium insertion behaviour of silver vanadium bronze

AU - Kawakita, Jin

AU - Katayama, Yasushi

AU - Miura, Takashi

AU - Kishi, Tomiya

PY - 1997/8/1

Y1 - 1997/8/1

N2 - Ag1+xV3O8 has been prepared by the ion exchange reaction in the molten salt of AgNO3 using Na1.2V3O8. This oxide has a similar layer structure to M1+xV3O8 (M = Li and Na), and its lattice parameter has been determined. Up to four moles of lithium (x = 4) in LixAg1.2V3O8 are accommodated electrochemically. The discharge process showed that after deposition of metallic silver by reduction of Ag(I) prior to V(V) and simultaneous occupation of the octahedral site by inserted Li(I), additional lithium was inserted into Li1.2V3O8. The charging process showed extraction of three lithiums from Li4V3O8 and no return of the silver element back to the original structure with oxidation.

AB - Ag1+xV3O8 has been prepared by the ion exchange reaction in the molten salt of AgNO3 using Na1.2V3O8. This oxide has a similar layer structure to M1+xV3O8 (M = Li and Na), and its lattice parameter has been determined. Up to four moles of lithium (x = 4) in LixAg1.2V3O8 are accommodated electrochemically. The discharge process showed that after deposition of metallic silver by reduction of Ag(I) prior to V(V) and simultaneous occupation of the octahedral site by inserted Li(I), additional lithium was inserted into Li1.2V3O8. The charging process showed extraction of three lithiums from Li4V3O8 and no return of the silver element back to the original structure with oxidation.

KW - Insertion

KW - Lithium

KW - Molten salts

KW - Silver

KW - Vanadium

UR - http://www.scopus.com/inward/record.url?scp=0031213316&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0031213316&partnerID=8YFLogxK

U2 - 10.1016/s0167-2738(97)00120-3

DO - 10.1016/s0167-2738(97)00120-3

M3 - Article

AN - SCOPUS:0031213316

SN - 0167-2738

VL - 99

SP - 71

EP - 78

JO - Solid State Ionics

JF - Solid State Ionics

IS - 1-2

ER -

Lithium insertion behaviour of silver vanadium bronze

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this