Morphological development and coordination change in the course of Cd2+ hydrolysis

Yuka Sakai; Daisuke Kawamoto; Takushi Yokoyama; Akane Miyazaki

doi:10.1246/bcsj.20180048

Morphological development and coordination change in the course of Cd²⁺ hydrolysis

Yuka Sakai
, Daisuke Kawamoto
, Takushi Yokoyama
, Akane Miyazaki

Research output: Contribution to journal › Article › peer-review

Abstract

Morphological development from nanowire to hexagonal platelet was observed for hydrolysis products of Cd(NO₃)₂ aqueous solution. 113Cd cross-polarization magic-angle spinning nuclear magnetic resonance spectroscopy and X-ray diffraction revealed that the morphological development corresponds to the change of coordination environment around Cd²⁺ from double salts containing nitrate ions to β-Cd(OH)₂.

Original language	English
Pages (from-to)	1249-1251
Number of pages	3
Journal	Bulletin of the Chemical Society of Japan
Volume	91
Issue number	8
DOIs	https://doi.org/10.1246/bcsj.20180048
Publication status	Published - 2018
Externally published	Yes

Keywords

Cd hydrolysis
CdNMR
Morphological control

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1246/bcsj.20180048

Cite this

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title = "Morphological development and coordination change in the course of Cd2+ hydrolysis",

abstract = "Morphological development from nanowire to hexagonal platelet was observed for hydrolysis products of Cd(NO3)2 aqueous solution. 113Cd cross-polarization magic-angle spinning nuclear magnetic resonance spectroscopy and X-ray diffraction revealed that the morphological development corresponds to the change of coordination environment around Cd2+ from double salts containing nitrate ions to β-Cd(OH)2.",

keywords = "Cd hydrolysis, CdNMR, Morphological control",

author = "Yuka Sakai and Daisuke Kawamoto and Takushi Yokoyama and Akane Miyazaki",

note = "Publisher Copyright: {\textcopyright} 2018 The Chemical Society of Japan.",

year = "2018",

doi = "10.1246/bcsj.20180048",

language = "English",

volume = "91",

pages = "1249--1251",

journal = "Bulletin of the Chemical Society of Japan",

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AU - Sakai, Yuka

AU - Kawamoto, Daisuke

AU - Yokoyama, Takushi

AU - Miyazaki, Akane

PY - 2018

Y1 - 2018

N2 - Morphological development from nanowire to hexagonal platelet was observed for hydrolysis products of Cd(NO3)2 aqueous solution. 113Cd cross-polarization magic-angle spinning nuclear magnetic resonance spectroscopy and X-ray diffraction revealed that the morphological development corresponds to the change of coordination environment around Cd2+ from double salts containing nitrate ions to β-Cd(OH)2.

AB - Morphological development from nanowire to hexagonal platelet was observed for hydrolysis products of Cd(NO3)2 aqueous solution. 113Cd cross-polarization magic-angle spinning nuclear magnetic resonance spectroscopy and X-ray diffraction revealed that the morphological development corresponds to the change of coordination environment around Cd2+ from double salts containing nitrate ions to β-Cd(OH)2.

KW - Cd hydrolysis

KW - CdNMR

KW - Morphological control

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U2 - 10.1246/bcsj.20180048

DO - 10.1246/bcsj.20180048

M3 - Article

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VL - 91

SP - 1249

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JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

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