Negative ion photoelectron spectroscopy of (benzene)n- (n = 53-124) and (toluene)n- (n = 33-139): Solvation energetics of an excess electron in size-selected aromatic hydrocarbon nanoclusters

Masaaki Mitsui; Atsushi Nakajima; Koji Kaya

doi:10.1063/1.1516793

Negative ion photoelectron spectroscopy of (benzene)_n^- (n = 53-124) and (toluene)_n^- (n = 33-139): Solvation energetics of an excess electron in size-selected aromatic hydrocarbon nanoclusters

Masaaki Mitsui, Atsushi Nakajima, Koji Kaya

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

A negative ion photoelectron spectroscopic study on the solvation energies of an excess electron in the size-selected aromatic hydrocarbon nanoclusters was presented. The second solvation layer was essential for stable binding of the excess electron in these clusters. The applicability of the generalized cluster size equation was examined in the nondipolar aromatic hydrocarbon systems.

Original language	English
Pages (from-to)	9740-9749
Number of pages	10
Journal	Journal of Chemical Physics
Volume	117
Issue number	21
DOIs	https://doi.org/10.1063/1.1516793
Publication status	Published - 2002 Dec 1

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.1516793

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Negative ion photoelectron spectroscopy of (benzene)_n^- (n = 53-124) and (toluene)_n^- (n = 33-139): Solvation energetics of an excess electron in size-selected aromatic hydrocarbon nanoclusters. / Mitsui, Masaaki; Nakajima, Atsushi; Kaya, Koji.
In: Journal of Chemical Physics, Vol. 117, No. 21, 01.12.2002, p. 9740-9749.

Research output: Contribution to journal › Article › peer-review

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Negative ion photoelectron spectroscopy of (benzene)_n^- (n = 53-124) and (toluene)_n^- (n = 33-139): Solvation energetics of an excess electron in size-selected aromatic hydrocarbon nanoclusters

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