TY - JOUR
T1 - Nitrous oxide oxidation catalyzed by ruthenium porphyrin complex
AU - Tanaka, Hirotaka
AU - Hashimoto, Kentaro
AU - Suzuki, Kyosuke
AU - Kitaichi, Yasunori
AU - Sato, Mitsuo
AU - Ikeno, Taketo
AU - Yamada, Tohru
PY - 2004/10
Y1 - 2004/10
N2 - Dinitrogen oxide was employed as a clean oxidant for various oxidations in the presence of a catalytic amount of dioxoruthenium tetramesitylporphyrin complex (Ru(tmp)(O)2). A variety of olefins, secondary alcohols, and benzyl alcohols were smoothly oxidized to the corresponding epoxides, ketones, and aldehydes in high yields. In the oxidation of 9,10-dihydroanthracene derivatives, the competitive reactions affording anthraquinones and anthracenes could be regulated by the reaction conditions. At a high temperature (200°C), anthraquinones were selectively produced, while the anthracenes were selectively produced by the addition of sulfuric acid.
AB - Dinitrogen oxide was employed as a clean oxidant for various oxidations in the presence of a catalytic amount of dioxoruthenium tetramesitylporphyrin complex (Ru(tmp)(O)2). A variety of olefins, secondary alcohols, and benzyl alcohols were smoothly oxidized to the corresponding epoxides, ketones, and aldehydes in high yields. In the oxidation of 9,10-dihydroanthracene derivatives, the competitive reactions affording anthraquinones and anthracenes could be regulated by the reaction conditions. At a high temperature (200°C), anthraquinones were selectively produced, while the anthracenes were selectively produced by the addition of sulfuric acid.
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U2 - 10.1246/bcsj.77.1905
DO - 10.1246/bcsj.77.1905
M3 - Article
AN - SCOPUS:8444246399
SN - 0009-2673
VL - 77
SP - 1905
EP - 1914
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 10
ER -