Novel C-3 Epimerization of Digitoxosides to Olivosides under Hydrogenolysis Conditions

Kazunobu Toshima; Kyoko Inagaki; Masaya Nakata; Shuichi Matsumura

doi:10.1055/s-1997-3269

Novel C-3 Epimerization of Digitoxosides to Olivosides under Hydrogenolysis Conditions

Kazunobu Toshima, Kyoko Inagaki, Masaya Nakata, Shuichi Matsumura

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The treatment of several β-digitoxosides with hydrogen in the presence of a catalytic amount of Raney-Ni (W4) in MeOH at 50°C under neutral conditions afforded the C-3 epimers, β-olivosides, in good yields.

Original language	English
Pages (from-to)	695-696
Number of pages	2
Journal	Synlett
Volume	1997
Issue number	6
DOIs	https://doi.org/10.1055/s-1997-3269
Publication status	Published - 1997 Jan 1

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1055/s-1997-3269

Cite this

@article{ede9e78428474619aae0927ce8e1231c,

title = "Novel C-3 Epimerization of Digitoxosides to Olivosides under Hydrogenolysis Conditions",

abstract = "The treatment of several β-digitoxosides with hydrogen in the presence of a catalytic amount of Raney-Ni (W4) in MeOH at 50°C under neutral conditions afforded the C-3 epimers, β-olivosides, in good yields.",

author = "Kazunobu Toshima and Kyoko Inagaki and Masaya Nakata and Shuichi Matsumura",

year = "1997",

month = jan,

day = "1",

doi = "10.1055/s-1997-3269",

language = "English",

volume = "1997",

pages = "695--696",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "6",

}

TY - JOUR

T1 - Novel C-3 Epimerization of Digitoxosides to Olivosides under Hydrogenolysis Conditions

AU - Toshima, Kazunobu

AU - Inagaki, Kyoko

AU - Nakata, Masaya

AU - Matsumura, Shuichi

PY - 1997/1/1

Y1 - 1997/1/1

N2 - The treatment of several β-digitoxosides with hydrogen in the presence of a catalytic amount of Raney-Ni (W4) in MeOH at 50°C under neutral conditions afforded the C-3 epimers, β-olivosides, in good yields.

AB - The treatment of several β-digitoxosides with hydrogen in the presence of a catalytic amount of Raney-Ni (W4) in MeOH at 50°C under neutral conditions afforded the C-3 epimers, β-olivosides, in good yields.

UR - http://www.scopus.com/inward/record.url?scp=1542468472&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=1542468472&partnerID=8YFLogxK

U2 - 10.1055/s-1997-3269

DO - 10.1055/s-1997-3269

M3 - Article

AN - SCOPUS:1542468472

SN - 0936-5214

VL - 1997

SP - 695

EP - 696

JO - Synlett

JF - Synlett

IS - 6

ER -

Novel C-3 Epimerization of Digitoxosides to Olivosides under Hydrogenolysis Conditions

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this