Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system

Makoto Mitani; Kunihiro Oouchi; Michiya Hayakawa; Tohru Yamada; Teruaki Mukaiyama

doi:10.1007/BF00294949

Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system

Makoto Mitani, Kunihiro Oouchi, Michiya Hayakawa, Tohru Yamada, Teruaki Mukaiyama

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Polymerization of ethylene and copolymerization of ethylene-propylene proceeded smoothly by using homometallic binuclear zirconium complex 1 or heterometallic binuclear zirconium-titanium complex 2/methylaluminoxane catalyst system. The molecular weight distributions of polymers obtained by the binuclear zirconium complexes were broader than that produced by mononuclear zirconium complex.

Original language	English
Pages (from-to)	677-682
Number of pages	6
Journal	Polymer Bulletin
Volume	35
Issue number	6
DOIs	https://doi.org/10.1007/BF00294949
Publication status	Published - 1995 Dec 1
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Condensed Matter Physics
Polymers and Plastics
Materials Chemistry

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10.1007/BF00294949

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title = "Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system",

abstract = "Polymerization of ethylene and copolymerization of ethylene-propylene proceeded smoothly by using homometallic binuclear zirconium complex 1 or heterometallic binuclear zirconium-titanium complex 2/methylaluminoxane catalyst system. The molecular weight distributions of polymers obtained by the binuclear zirconium complexes were broader than that produced by mononuclear zirconium complex.",

author = "Makoto Mitani and Kunihiro Oouchi and Michiya Hayakawa and Tohru Yamada and Teruaki Mukaiyama",

year = "1995",

month = dec,

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doi = "10.1007/BF00294949",

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volume = "35",

pages = "677--682",

journal = "Polymer Bulletin",

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TY - JOUR

T1 - Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system

AU - Mitani, Makoto

AU - Oouchi, Kunihiro

AU - Hayakawa, Michiya

AU - Yamada, Tohru

AU - Mukaiyama, Teruaki

PY - 1995/12/1

Y1 - 1995/12/1

N2 - Polymerization of ethylene and copolymerization of ethylene-propylene proceeded smoothly by using homometallic binuclear zirconium complex 1 or heterometallic binuclear zirconium-titanium complex 2/methylaluminoxane catalyst system. The molecular weight distributions of polymers obtained by the binuclear zirconium complexes were broader than that produced by mononuclear zirconium complex.

AB - Polymerization of ethylene and copolymerization of ethylene-propylene proceeded smoothly by using homometallic binuclear zirconium complex 1 or heterometallic binuclear zirconium-titanium complex 2/methylaluminoxane catalyst system. The molecular weight distributions of polymers obtained by the binuclear zirconium complexes were broader than that produced by mononuclear zirconium complex.

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U2 - 10.1007/BF00294949

DO - 10.1007/BF00294949

M3 - Article

AN - SCOPUS:0010929827

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JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 6

ER -

Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system

Abstract

ASJC Scopus subject areas

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