Photo-control of the electronic states of Iron coordinated to photo-responsive polyaniline

Kazuyoshi Oshida; Yasuaki Einaga

doi:10.1016/j.tsf.2007.01.029

Photo-control of the electronic states of Iron coordinated to photo-responsive polyaniline

Kazuyoshi Oshida, Yasuaki Einaga

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Fe³⁺ doped polyaniline (PANI) films containing azobenzene derivatives in the side chain have been prepared. Photoisomerization of the azobenzene derivative in the PANI films was observed at room temperature. Furthermore, ⁵⁷Fe Mössbauer measurements showed that the ligand-metal bond distance and the symmetry around the Fe³⁺ were influenced by the photoisomerization.

Original language	English
Pages (from-to)	5484-5489
Number of pages	6
Journal	Thin Solid Films
Volume	515
Issue number	13
DOIs	https://doi.org/10.1016/j.tsf.2007.01.029
Publication status	Published - 2007 May 7

Keywords

Azobenzene
Fe Mössbauer measurement
FeCl-doped PANI

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Surfaces and Interfaces
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/j.tsf.2007.01.029

Cite this

@article{b0946dcbeb6d4090ad53c9ac44eb1646,

title = "Photo-control of the electronic states of Iron coordinated to photo-responsive polyaniline",

abstract = "Fe3+ doped polyaniline (PANI) films containing azobenzene derivatives in the side chain have been prepared. Photoisomerization of the azobenzene derivative in the PANI films was observed at room temperature. Furthermore, 57Fe M{\"o}ssbauer measurements showed that the ligand-metal bond distance and the symmetry around the Fe3+ were influenced by the photoisomerization.",

keywords = "Azobenzene, Fe M{\"o}ssbauer measurement, FeCl-doped PANI",

author = "Kazuyoshi Oshida and Yasuaki Einaga",

note = "Funding Information: This work was supported by a Grant-in-Aid for Scientific Research on Priority Area (417) and by the 21st Century COE program “KEIO Life Conjugate Chemistry” from the Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of the Japanese Government.",

year = "2007",

month = may,

day = "7",

doi = "10.1016/j.tsf.2007.01.029",

language = "English",

volume = "515",

pages = "5484--5489",

journal = "Thin Solid Films",

issn = "0040-6090",

publisher = "Elsevier",

number = "13",

}

TY - JOUR

T1 - Photo-control of the electronic states of Iron coordinated to photo-responsive polyaniline

AU - Oshida, Kazuyoshi

AU - Einaga, Yasuaki

N1 - Funding Information: This work was supported by a Grant-in-Aid for Scientific Research on Priority Area (417) and by the 21st Century COE program “KEIO Life Conjugate Chemistry” from the Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of the Japanese Government.

PY - 2007/5/7

Y1 - 2007/5/7

N2 - Fe3+ doped polyaniline (PANI) films containing azobenzene derivatives in the side chain have been prepared. Photoisomerization of the azobenzene derivative in the PANI films was observed at room temperature. Furthermore, 57Fe Mössbauer measurements showed that the ligand-metal bond distance and the symmetry around the Fe3+ were influenced by the photoisomerization.

AB - Fe3+ doped polyaniline (PANI) films containing azobenzene derivatives in the side chain have been prepared. Photoisomerization of the azobenzene derivative in the PANI films was observed at room temperature. Furthermore, 57Fe Mössbauer measurements showed that the ligand-metal bond distance and the symmetry around the Fe3+ were influenced by the photoisomerization.

KW - Azobenzene

KW - Fe Mössbauer measurement

KW - FeCl-doped PANI

UR - http://www.scopus.com/inward/record.url?scp=33947712039&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33947712039&partnerID=8YFLogxK

U2 - 10.1016/j.tsf.2007.01.029

DO - 10.1016/j.tsf.2007.01.029

M3 - Article

AN - SCOPUS:33947712039

SN - 0040-6090

VL - 515

SP - 5484

EP - 5489

JO - Thin Solid Films

JF - Thin Solid Films

IS - 13

ER -

Photo-control of the electronic states of Iron coordinated to photo-responsive polyaniline

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this